Authors reported an effective path to increase the electrical conductivity while to decrease the thermal conductivity, and thus to enhance the ZT value by nano-inclusions. By this method, the ZT value of Nb-doped SrTiO3 was enhanced 9-fold by yttria stabilized zirconia (YSZ) nano-inclusions. YSZ inclusions, located inside grain and in triple junction, can reduce the thermal conductivity by effe...

Introduction Electrochemically induced oxygen diffusion on electrode surfaces plays an important role in solid state electrochemistry, especially in the context of electrochemical promotion of catalysis (EPOC), also referred to as non-faradaic electrochemical modification of catalytic activity (NEMCA) [1]. The Pt(O2)|YSZ system is a model system in solid state electrochemistry as well as for EP...

The properties of plasma sprayed Y-Ba-Cu-O coatings deposited on metallic substrates are studied. Stainless steel, nickel steels and pure nickel are used as substrate. Y-Ba-Cu-O deposited on stainless steel and nickel steel reacts with the substrate. This interaction can be suppressed by using an yttria-stabilized zirconia (YsZ) diffusion barrier. However, after heat treatment the Y-Ba-Cu-O lay...

Thermal and environmental barrier coatings are important components of current and future energy systems. Such coatings – applied to hot, metallic surfaces in combustors, heat exchanger and turbines – increase the allowable operating temperature and increase the efficiency of the energy system. Because of its low thermal conductivity and high thermal expansion yttria-stabilized zirconia (YSZ) i...

This paper presents low cycle fatigue (LCF) life prediction of a coated and uncoated exhaust manifolds. First Solidworks software was used to model the exhaust manifolds. A thermal barrier coating system was applied on the tubes c of the exhaust manifolds, consists of two-layer systems: a ceramic top coat (TC), made of yttria stabilized zirconia (YSZ), ZrO2-8%Y2O3 and also a metallic bond coat ...

CMC's reinforced by SiC-based fibers achieve high toughness and damage tolerance through the disposal of weak fiber coating which can deflect cracks and promote debonding at the fiber/matrix region. Refractory oxide-based systems are considered as the most promising ones for this purpose. Sols of zirconia, including stabilized zirconia were used as simple and readily processable precursors for ...

Transmission electron microscopy (TEM) is a very powerful technique for materials characterization, providing information relating to morphology, composition, and crystal structure. Selected area diffraction patterns (SADPs) are crystallographic data that can be obtained using a TEM instrument. Conventional identification through SADP/TEM is tricky and tedious, thereby increasing the difficulty...

Using first principles simulations and the Monte Carlo method, the optimal structure of the triple-phase boundaries (TPB) of the Ni/Yttria-Stabilized Zirconia (YSZ) anode in solid oxide fuel cells (SOFCs) is determined. Based on the new TPB microstructures we reveal different reaction pathways for H2 and CO oxidation. In contrast to what was believed in previous theoretical studies, we find tha...

The fabrication process of ceramic yttria-stabilized zirconia (YSZ) and nickel oxide nanofibers by electrospinning is reported. The preparation of hollow YSZ nanofibers and aligned nanofiber arrays is also demonstrated. The influence of the process parameters of the electrospinning process, the physicochemical properties of the spinning solutions, and the thermal treatment procedure on spinnabi...

Mechanosynthesis of La1-xSrxMnO3 (x = 0, 0.25, 0.5, 0.75 and 1) was carried out at room temperature from stoichiometric mixtures of La2O3, Mn2O3 and SrO, obtaining monophasic powders with the perovskite structure. Physical properties of these materials and their chemical compatibility with the electrolyte yttria stabilized zirconia (YSZ), which depend strongly on the La/Sr ratio, were evaluated...