In this study, we report removal of Diclofenac (DCF) through heterogeneous Fenton process using Fe-ZSM-5 catalyst. The parent catalyst was prepared by hydrothermal technique. Fe species were introduced by wet impregnation. Characterization of the catalysts was carried out using XRD, FT-IR, FE-SEM, N2 adsorption-desorption, NH3-TPD, and acidimetric-alkalimetric titration. The bimetallic catalyst...

Ruthenium-based bimetallic electrocatalysts with non-noble metals such as Ti, Cr, Fe, Co and Pb were synthesized on a porous carbon support sing a chelation process. Rotating ring disk electrode measurements indicated that RuFeNx/C showed the catalytic activity and selectivity toward he four-electron reduction of oxygen to water comparable to those of the conventional Pt/C catalysts. The perfor...

Dinickel bisphenoxyiminato complexes based on highly substituted p- and m-terphenyl backbones were synthesized, and the corresponding atropisomers were isolated. In the presence of a phosphine scavenger, Ni(COD)2, the phosphine-ligated syn-dinickel complexes copolymerized α-olefins and ethylene in the presence of amines to afford 0.2-1.3% α-olefin incorporation and copolymerized amino olefins a...

Hydrogenolysis and dehydrogenation of propane were studied over model nickel–gold catalysts. The supported model Ni–Au catalysts were prepared by depositing Ni and Au onto a planar silica film. Infrared reflection absorption spectroscopic data showed that isolated Ni sites appeared and became dominant on the surface with the addition of Au to Ni. For the conversion of propane in the presence of...

A bimetallic heme-DNA cofactor, containing an iron and a copper center, was synthesized for the design of novel hybrid catalysts for stereoselective synthesis. The cofactor was used for the reconstitution of apo-myoglobin. Both the cofactor alone and its myoglobin adduct were used to catalyze a model Diels Alder reaction. Stereoselectivity of this conversion was analyzed by chiral HPLC. Reactio...

Bimetallic (Pd-Cu, Pd-Sn) nanoparticles supported on structured fibrous carbons (activated carbon fibers and carbon nanofibers grown on sintered metal fibers) were tested in denitrification of natural polluted water by hydrogen (a batch and continuous mode). Dependence of the activity/selectivity on catalyst chemical composition, promoter nature and metal particle size was studied. Sn-modified ...

ZnO nanowires have been grown by chemical vapour deposition (CVD) using PdZn bimetallic nanoparticles to catalyse the process. Nanocatalyst particles with mean particle diameters of 2.6 ± 0.3 nm were shown to catalyse the growth process, displaying activities that compare well with those reported for sputtered systems. Since nanowire diameters are linked to catalyst morphology, the size-control...

High-quality single-walled carbon nanotubes (SWCNTs) have been synthesized from H2–CH4 mixtures on a MgO-supported bimetallic Mo/Co catalyst using microwave plasma-enhanced chemical vapor deposition (PECVD). Reaction parameters including temperature, H2:CH4 ratio, plasma power, and synthesis time have been examined to assess their influence on SWCNT synthesis. Raman spectroscopy and high-resolu...