In this study, a hydroxyl-functionalized ionic liquid 1-hydroxyethyl-3-methyl imidazolium bis(trifluoromethylsulfonyl)imide ([OHEMIM][NTf2]) and tri-n-butyl phosphate (TBP) were used as co-extraction reagent extractant, respectively, to improve the extraction efficiency of Li+ separation factor Li–Mg from brine with high Mg/Li ratio. The is 94.2% 539 under optimal condition. washing Mg2+ K+ clo...

The homologous series of the ionic liquids 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, [CnC1im][NTf2] (n = 2,4,6,8 and 10) was studied by polarization-resolved second harmonic scattering (SHS). analysis polarization plots clearly demonstrates that SHS response is dominated an octupolar contribution. Orientational correlations are observed on nanometer scale in all investigate...

The dynamics of a series of small molecule probes with increasing alkyl chain length: water, methanol, and ethanol, diluted to low concentration in the room temperature ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, was investigated with 2D infrared vibrational echo (2D IR) spectroscopy and polarization resolved pump-probe (PP) experiments on the deuterated hydroxyl...

Highly fluorinated fullerenes with a chemical composition of C60F48 have been prepared and characterized. Their solubility the new nanomaterials in ionic liquid (IL) has compared raw C60. Fluorination may appear as convenient method to enhance carbonaceous based anion IL. Indeed, ability 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BmIm][NTf2]), solubilize C60 was investigate...

Zinc oxide (ZnO) is a semiconductor with various physicochemical properties allowing its use in wide range of technological applications. The aim this work to study nanocrystalline ZnO thin-film deposited using zinc salt which dissolved pure ionic liquids (ILs). latter play dual role: solvent and supporting electrolyte. Most ILs have large electrochemical window sufficient conductivity. In work...

Utilization of ionic liquids (ILs) for carbon dioxide (CO2) capture is continuously growing, and further understanding the factors that influence its solubility (notably new ILs) crucial. Herein, CO2 absorption two 1,2,4-triazolium-based ILs was compared with imidazolium-based Ils different anions, namely bis(trifluoromethylsulfonyl)imide, tetrafluoroborate, glycinate. The capacity determined u...

Azobenzene (azoB) is a promising anode active material for nonaqueous redox flow battery (NARFB), but the performance assembled with azoB rather poor. Here, we show that rate of NARFB and 2,5-di-tert-butyl-1-methoxy-4-[2?-methoxyethoxy] benzene (DBMMB) as anolyte catholyte materials can be significantly enhanced by optimizing solvent, supporting electrolyte, membrane. The synergistic interactio...