Inverse gas chromatography, (IGC), has been used to measure interaction parameters in two low-molar-mass liquid crystals and a polymer substituted with the same mesogenic group. Solubility parameters have been calculated. The IGC method is shown to be applicable to this class of compounds and to give meaningful values over a range of temperatures.

This paper addresses dynamic optimization of a large-scale natural gas processing plant through the formulation of rigorous unit dynamic models. The resulting differential-algebraic equation (DAE) optimization problem is solved with an advanced simultaneous strategy that transforms the original problem into a nonlinear program. Emphasis has been given to detailed thermodynamic and solubility ca...

a r t i c l e i n f o Probability distribution functions (PDF) can be useful descriptors for the random structure of non-crystalline solids. The lognormal PDF has provided a good description of the distribution of interstitial site sizes in non-crystalline solids, both metallic and nonmetallic. The utility of this descriptor to characterize the ring statistics of vitreous silica under a wide ra...

Perfluorocarbon (PFC) emulsions are halogen-substituted carbon nonpolar oils with resultant enhanced dissolved respiratory gas (O(2), N(2), CO(2), nitric oxide) capabilities. In the first demonstration of enhanced O(2) solubility, inhaled PFC could sustain rat metabolism. Intravenous emulsions were then trialed as "blood substitutes." In the last 10 yr, biocomputational modeling has enhanced ou...

Certain heavy oils which foam under severe depressurization give rise to increased recovery factor and an increased rate of production under solution gas drive. These oils not only stabilize foam, but also stabilize dispersion of gas bubbles at lower volume ratios. The way this phenomenon is related to the chemistry of the oil and its viscosity is presently not understood. We present here a mat...