the object of this work is solubility correlation and prediction of co2 and h2s in various aqueous alkanolamines using the electrolyte cubic square-well equation of state (ecsw eos) [haghtalab, a.,mazloumi, s. h., (2009a), fluid phase equilib.,285,96-104]. the eeos systematically is applied to describe the solubility of acid gases in various alkanolamine solutions, including mdea, mea, dea, amp...

In this study, a time-dependent 2D axisymmetric model of a multilayer hollow fiber composite membrane for gas separation is proposed. In spite of the common multilayer membranes, which a dense layer coated on a porous support layer and subjected into the feed stream, here, the porous support is exposed to the feed gas. In this regard, the governing equations of species transport are developed f...

in this work, the pc-saft equation of state (eos) has been used to model the solubility of acid gases (co2 and h2s) in two imidazolium-based ionic liquids (ils) ([c8-mim][pf6] and [c8-mim][tf2n]). parameters of pure ils were estimated using experimental densities. two strategies were considered to model densities of pure ils. in strategy 1, ils were modeled as nonassociating compounds and in st...

Hydrocarbons are sparingly soluble in aqueous solvents and to a first approximation their solubility can be described by the traditional Henry’s Law, which linearly relates the mole fraction in water to gas-phase partial pressure. The presence of amines in the aqueous phase increases hydrocarbon solubility over that in water, an effect referred to as “salting-in”. Commercial amine treating solu...

Natural gas sweetening is an important process which is used for treatment of sour gases. The measurement of solubility is also considered in most sweetening processes such as that of Townsend process. Therefore, experimental measurements would be helpful to determine the equilibrium data under actual equilibrium conditions for the gas treatment plants. In this research solubility of hydrogen s...

A novel approach using a semipermeable Teflon AF-2400 tube-in-tube membrane contactor was developed for the measurement of gas solubility in organic solvents. This membrane ensures gas saturation of liquids in continuous flow at a specific pressure and temperature. After liquid decompression, the amount of gas outgassed was measured with a bubble meter and used for solubility calculation. The p...

the density and viscosity of carbonated aqueous 35wt% methyldiethanolamine solution were experimentally measured accompanied with the solubility of co2 at temperatures from (303.15 to 363.15) k and pressures up to 0.8 mpa using the new setup developed in our laboratory.it was observed that both density and viscosity of mixtures decrease by increasing temperature and increase by increasing acid ...

This critical review provides a critical discussion of the current state of knowledge of the key factors influencing the solubility of gases in ionic liquids (ILs), including sample purity, experimental methodology, "molecular" characteristics of ILs, temperature and pressure. The review starts with a brief introduction to the current developments and the existing problems in the studies of the...