NiO is a promising electrode material for supercapacitors. Herein, the novel vertically standing nanosized NiO encapsulated in graphene layers (G@NiO) are rationally designed and synthesized as nanosheet arrays. This unique vertical standing structure of G@NiO nanosheet arrays can enlarge the accessible surface area with electrolytes, and has the benefits of short ion diffusion path and good ch...

A simple donor-acceptor linked dyad, 9-mesityl-10-methylacridinium ion (Acr(+)-Mes) was incorporated into nanosized mesoporous silica-alumina to form a composite, which in acetonitrile is highly dispersed. In this medium, upon visible light irradiation, the formation of an extremely long-lived electron-transfer state (Acr(•)-Mes(•+)) was confirmed by EPR and laser flash photolysis spectroscopic...

A theory for the prediction of the size dependence of torsional rigidities of nanosized structural elements is developed. It is shown that, to a very good approximation, the torsional rigidity (D) of a nanosized bar differs from the prediction of standard continuum mechanics (Dc) as (D−Dc)/Dc = Ah0/a where A is a non-dimensional constant, a is the size scale of the cross-section of the bar and ...

The atomic scale homogeneity of Ce and Zr oxygen bonds represents the main reason for enhanced total oxygen storage capability of CeO2-ZrO2 (Ce/Zr = 1) as compared to that of CeO2. Here, we demonstrate that the addition of 10% Eu(3+) by wet impregnation on preformed nanosized CeO2-ZrO2 (Ce/Zr = 1) followed by calcination induces a remarkable homogeneity of 10% Eu(3+)-CeO2-ZrO2 solid solution. B...

Excellent field electron emission properties of a diamond/CoSi(2)/Si quantum well nanostructure are observed. The novel quantum well structure consists of high quality diamond emitters grown on bulk Si substrate with a nanosized epitaxial CoSi(2) conducting interlayer. The results show that the main emission properties were modified by varying the CoSi(2) thickness and that stable, low-field, h...

Coatings prepared from nanosized powders were obtained by spraying ethanol-based colloidal solutions into a plasma plume. The powders investigated included 40 nm γ -Al2O3, 75 nm 8 wt% Y2O3-ZrO2, and 750 nm 25 wt% CeO2-ZrO2. Spray distances from approximately 50 to 63 mm were required to achieve significant coating deposition. As observed in the TEM, the typical lamella morphology of air plasma ...

Human beings have been exposed to airborne nanosized particles throughout their evolutionary stages, and such exposures have increased dramatically over the last century. The rapidly developing field of nanotechnology will result in new sources of this exposure, through inhalation, ingestion, and injection. Although nanomaterials are currently being widely used in modern technology, there is a ...

In the present study, methods to enhance the oxygen reduction reaction (ORR) activity of sub-nanosized Pt clusters were investigated in a theoretical manner. Using ab initio molecular dynamics and Monte Carlo simulations based on density functional theory, we have succeeded in determining the origin of the superior ORR activity of Pt12 compared to that of Pt13. That is, it was clarified that th...