نتایج جستجو برای: thermoregulated ionic liquid biphasic system
تعداد نتایج: 2455607 فیلتر نتایج به سال:
the density (d), speed of sound (u) and electrolytic conductivity (λ) for systems containing acetaminophen, ionic liquid {1-octyl-3-methyl imidazolium bromide, [omim] br} and water have been measured at t = 293.15-308.15 k. the measured data have been applied to calculate, standard partial molar volume ( ), hepler’s constant , apparent molar isentropic compressibility (kφ), transfer volume ( ),...
Aqueous biphasic systems (ABSs) provide a sustainable and efficient alternative to conventional liquid-liquid extraction techniques with volatile organic solvents, and can be used for the extraction, recovery, and purification of diverse solutes. In this work, and for the first time, ABSs composed of poly(ionic liquid)s (PILs) and inorganic salts were measured at 25 °C and atmospheric pressure....
Transfers of solutes from an aqueous solution to ionic liquid and vice versa has been well studied for years. On the other hand, influence transferred on liquid's network is not yet evaluated. Therefore, we focus - biphasic system composed two immiscible solutions containing N-H acid bis(trifluoromethylsulfonyl) imide [C4mim][Tf2N] liquid. After mixing separation phases, a part water, H3O+, [Tf...
The ionic liquid, N,N,N,N-tetramethylguanidiniumtriflate (TMGTf) was found to be an efficient catalyst solvent for Henry reaction between nitromethane and isatin derivatives to provide 3-hydroxy-3-(nitromethyl)indolin-2-one under mild conditions. The ionic liquid amenable to successive recycling without appreciable decrease in activity. Synthesized compounds have been screened for their anti-di...
α-amino nitriles are synthesized in a one-pot, three-component coupling of aldehydes (or ketones), aniline, and trimethylsilyl cyanide using a catalytic amount of choline chloride.2zncl2 as a bio lewis acidic ionic liquid. mild lewis acidic characteristic of this ionic liquid allows efficient synthesis of α-amino nitriles from acid sensitive aldehydes.
an efficient and green method for the synthesis of pyrano[3,2-c]chromene or pyrano[4,3-b]pyrone derivatives is described by using a three-component condensation process of malononitrile, aldehyde, and 4-hydroxycoumarine or 4-hydroxypyrone in [bmim]bf4-licl as an ionic liquid.
one-pot preparation of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles has been conducted in the presence of poly(4-vinylpyridinium butane sulfonic acid) hydrogen sulfate, p(4vpbsa)hso4, as an efficient dual acidic catalyst under solvent-free conditions. reusability of the catalyst, easy work-up procedure, eco-friendly reaction conditions, short reaction times and high yields of th...
in the present investigation, a novel adsorbent, ionic liquid modified magnetic nanoparticles (il-fe3o4), was successfully synthesized and characterized by ft-ir spectroscopy, thermogravimetric analysis (tga), xrd analysis, scanning electron microscopy (sem) and theory of brunauer, emmett, and teller (bet) for removal of reactive orange 122 (ro-122) from aqueous solutions. the effects of variou...
Palladium nanoparticles have been deposited onto imidazolium bromide-functionalized ionic MWCNTs through hydrogen reduction of Na2PdCl4 in water without aid of surfactants under extremely mild conditions, and combined with an ionic liquid to create a new recyclable ionic liquid-based catalytic system allowing up to 50 times recycling.
SBA-15 was prepared and then functionalized with N-methyl-N’-propyltrimethoxysilyl imidazolium chloride as ionic liquid moiety. The ionic liquid functionalized SBA-15 (SBA-IL) was characterized by different analytical techniques including FT-IR, N2 adsorption-desorption, TGA and SEM image. According to the obtained results it was found that the organic groups were g...
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