background : the present paper aims to study the effect of human and urban activities on the quality of groundwater within the city of khoy in terms of heavy metals, chemical salts, and minerals from the geological formations of this region. methods : samples were provided from 32 pumping wells and the concentration of heavy metals ( cd, cu, mn, pb, zn, fe, as, and b), the main ions (hco 3 ,so ...

A set of complex tricyclic compounds containing several functional groups and multiple stereogenic centers has been prepared in only two steps with excellent diastereo- enantioselectivities. The synthesis takes advantage the highly versatile enantioselective Pd-catalyzed allylic substitution simple cyclic acetates or carbonates to form chiral 1,6-, 1,7- 1,8-enynes, which are then diastereoselec...

effects of sodium salt solutions on physicochemical and sensory characteristics of refrigerated persian sturgeon (acipenser persicus) fillets during 12 days of storage were investigated. fillets were dipped in solutions (2.5% w/v) of sodium acetate (sa), sodium lactate (sl), sodium citrate (sc) and distilled water (as control) for 10 minutes and then packaged. an assessment of tbars, ffa, ph, h...

iodine as a trace micronutrient has important role in body physiology and its sufficient intake is essential for synthesize and secrete adequate amounts of thyroid gland hormones which influenced all periods of human life including fetal, childhood and adolescence. the aim of this study was to evaluate iodine concentration in marketed edible salt samples in lorestan province, comparing with exi...

The ability of Pd(II) complexes derived from 2,6-pyridinedicarboxylic acids to catalyze homogeneous regioselective aerobic oxidation of 5- and 6-substituted 8-methylquinolines in AcOH-Ac(2)O solution to produce corresponding 8-quinolylmethyl acetates in high yield was demonstrated; corresponding 8-quinoline carboxylic acids are minor reaction products.

A new asymmetric total synthesis of a phenanthroindolizidine alkaloid (S)-tylophorine is reported, which features a catalytic asymmetric allylation of aldehydes and an unexpected one-pot DMAP promoted isocyanate formation and Lewis acid catalyzed intramolecular cyclization reaction. In addition, White's direct C-H oxidation catalyst system converting monosubstituted olefins to linear allylic ac...

The kinetic enzymatic resolution of azo acetates via aminolysis with Candida antarctica lipase B has been investigated using benzylamine as amine component. The products obtained from this biotransformation in high enantiomeric purity can serve as valuable precursors for various amino alcohols, as exemplified by the synthesis of the serotonin reuptake inhibitor (S)-(+)-cericlamine.