In this study, in-situ bulk polymerization was investigated for obtaining flame retardant polystyrene (PS). The halogenated and phosphoric compounds were used as flame retardant additives and Perkadox 30 was used as a synergist. The flammability of the PS was evaluated by thermogravimetric analyzer (TGA), limiting oxygen index (LOI) and UL-94 tests. The results show that polymerization process ...

Background & Aims: Aflatoxin M1 is one of the most important toxins present in milk and the product of aflatoxin B1 metabolism in liver microsomes. The aim of this project was to study the aflatoxin M1 adsorption ability of polystyrene-hydroxyapatite nanocomposite. Methods: First, the probability of aflatoxin M1 adsorption by the nanocomposite was evaluated using the HyperChem simulation softwa...

CONTEXT To demonstrate an EUS-guided biliary drainage in patient with gastrointestinal tract modified surgically. CASE REPORT An EUS guided access to the left intra hepatic duct, followed by an antegrade passage of a partially self-expandable metal stent that was removed by using an enteroscope, in one patient with hepatico-jejunal anastomosis. There were no early or delayed complications and...

Esophagojejunal anastomosis fistula is the main complication after a total gastrectomy. To avoid a complex procedure on friable inflamed perianastomotic tissues, a coated self-expandable stent is mounted at the site of the anastomotic leak. A complication of stenting procedure is that it might lead to distal esophageal stenosis. However, another frequently encountered complication of stenting i...

OBJECTIVE to evaluate the use of endoscopic self-expandable metallic prostheses in the treatment of fistulas from sleeve gastrectomy and Roux en y gastric bypass. METHODS all patients were treated with fully coated auto-expandable metallic prostheses and were submitted to laparoscopic or CT-guided drainage, except for those with intracavitary drains. After 6-8 weeks the prosthesis was removed...

Dendronized polystyrene having peripheral bromo groups was prepared from the dendronization of unfunctionalized polystyrene with dendritic diarylcarbenium ions bearing peripheral bromo groups using the "cation pool" method. The palladium-catalyzed amination of the peripheral bromo groups with diarylamine gave dendronized polystyrene equipped with peripheral triarylamines, which exhibited two se...

Chemical kinetics on thermal decomposition of polystyrene was studied by integrating the non-isothermal differential and integral methods. For decomposition of polystyrene in environment with only nitrogen, a mass loss stage was found at 282.9C to 398.2C. The maximum mass-loss rate was at 372.4C. Kinetic analysis results indicated that it is a first-order chemical reaction. Thermal decompositio...