A diastereoselective and modular approach to the synthesis of the 3-hydroxymethyl-2,3,5,6,7,7a-hexahydro-1H-pyrrolizine-1,2,7-triol structure, characteristic of several natural pyrrolizidine natural products, has been developed. This approach culminated in the synthesis of (-)-7-epiaustraline and (+)-1,7-diepiaustraline. The oxazolidinone group has been found to be a useful protecting group in ...

The cis-hydrindane motif is found in a number of natural products that display important biological activity. A flexible, stereoselective approach to the framework has been developed that features highly diastereoselective, SmI(2)-mediated cyclisations. The strategy has been exploited in the first synthesis of the proposed structure of faurinone and an approach to the skeleton of the antibacter...

abstract with consideration to the resource limitation, it seems necessary to design cropping pattern scientifically in order to increase productivity of production factors and to decrease production average costs. this studyaimed at identifying the optimum cropping pattern based on comparative advantage in three counties of ilam province including darreh shahr, ivan, and shirvan chardaval. to ...

This study aims to overview how local fashion products in developing countries can increase consumer purchase intentions for their digitally. Apply a quantitative approach with online data collected from 100 respondents through questionnaire that was distributed those who had been selected. The analysis results show social media marketing and brand management affect buying interest collaboratio...

introduction: agriculture as one of old sectors of economy has been important role in the supply food for peoples and raw materials. globalization causes rapid growth of world trade and reduces information and communications costs. globalization and rapid growth of trade increases the potential benefits of trade for agriculture from various aspects. the potential benefits of trade for agricultu...