نتایج جستجو برای: kinetic investigation

تعداد نتایج: 411072  

A. Manuchehrifar S.F. Abtahi,

In this study, the natural frequencies and mode shapes of beams without cracks and cracked Timoshenko beams is calculated with different boundary conditions using finite element method. The energy method is used to solve the equations. Hardness and softness matrices for Timoshenko beam without crack are obtained by solving the potential and kinetic energy equations. Then for investigation of cr...

In this study, reactions of the simple cycloalkynes with substituted Nitrile Oxides, by DFT method will be discussed. The investigation of the structural properties, theoretical thermodynamic and kinetic data, i.e., the activation free energies(DG*), the free energies changes of reaction(DrG) and rate constants of the reactions (k) in 298 K and effects of Electron-withdrawing and...

In this investigation Rayleigh-Ritz variational method has been applied to determine the least natural frequency coefficient for the title problem. Classical plate theory assumptions have been used to calculate strain energy and kinetic energy. Coordinate functions are combination of polynomials which satisfy boundary conditions at the outer boundary and trigonometric terms. In the second part ...

2008
YU KAWAKAMI

In this paper, we prove effective estimates for the number of exceptional values and the totally ramified value number for the Gauss map of pseudo-algebraic minimal surfaces in Euclidean four-space and give a kind of unicity theorem.

1994
Wim De Pauw Doug Kimelman John M. Vlissides

This paperdescribes awayof organizing information about an object-orientedprogram’s execution. The context is our system for visualizing that execution. The critical constraints are completeness, compactness, and efficient retrieval. We describe our design and how it meets these constraints.

Journal: :The Journal of biological chemistry 1982
H W Weber M M Appleman

Chromatographic analysis of a soluble extract of rat adipose tissue on DEAE-Sephacel resolves four distinct peaks of 3':5'-nucleotide phosphodiesterase (EC 3.1.4.17) activity. Kinetic investigation indicates that two of these fractions have a high affinity for cyclic AMP and show negative cooperative kinetic behavior at high substrate concentration. They differ in the degree of inhibition by cy...

Journal: :The journal of physical chemistry letters 2014
Y Kawarai Th Weber Y Azuma C Winstead V McKoy A Belkacem D S Slaughter

We report a combined experimental and theoretical investigation of dissociative electron attachment (DEA) to the nucleobase uracil. Using ion momentum imaging experiments employing a DEA reaction microscope we have measured 3-dimensional momentum distributions of specific anionic fragments following DEA to uracil by 6 eV electrons. From the measured anion fragment kinetic energy we determine th...

Journal: :Zeitschrift fur Naturforschung. Teil C: Biochemie, Biophysik, Biologie, Virologie 1973
T J Fitzgerald

Acid-catalyzed hydrolysis of the methox-ytropone moiety of colchicine has been shown to proceed at a greater rate than in the case of isocolchicine1. (Struc­ tures are shown in Table I.) No interpretation of this rate difference has been offered. And, while a mecha­ nism for the acid-catalyzed hydrolysis of 2 -methoxytropone has been proposed2, no kinetic data on this type of reaction either fo...

2004
Joshua D. Spencer

Fumarase C is responsible for the reversible hydration/dehydration of S-malate to fumarate during the catabolic Kreb’s cycle. Using PCR based site-directed mutagenesis; two active site mutants of fumarase C have been constructed. The recombinant enzymes, S139A and S140A, were purified using metal affinity chromatography and subjected to kinetic analysis and X-ray crystallization. The kinetic in...

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