In this paper, the f(alpha) conversion functions for random scission mechanisms have been proposed to allow for the construction of generalized master plots suitable for these kinds of mechanisms. The master plots have been validated by their application to simulated data and to the thermal degradation of poly(butylene terephthalate), polyethylene, and poly(tetrafluoroethylene).

This study focused on kinetic modeling of a specific type of multistep heterogeneous reaction comprising exothermic and endothermic reaction steps, as exemplified by the practical kinetic analysis of the experimental kinetic curves for the thermal decomposition of molten ammonium dinitramide (ADN). It is known that the thermal decomposition of ADN occurs as a consecutive two step mass-loss proc...

Several types of kinetics-based thermal degradation models were evaluated to predict strength loss of fire-retardant-treated wood as a function of cumulative thermal exposure. The data were taken from previous tests and reports on small, clear specimens of southern pine treated with six different fire-retardant chemicals and subjected to various durations of a steady-state exposure at different...

Adopting the theoretical framework for the generalized fishbonelike dispersion relation, an extended hybrid magnetohydrodynamics gyrokinetic simulation model has been derived analytically by taking into account both thermal ion compressibility and diamagnetic effects in addition to energetic particle kinetic behaviors. The extended model has been used for implementing an extended version of hyb...

Thermogravimetric analysis was carried out to investigate the thermal degradation of High Density Poly Ethylene (HDPE) short fibers reinforced epoxy composites. Three composites with 5, 10 and 15 % by weight of HDPE short fiber composition were prepared using epoxy as matrix material. The HDPE short fiber used as reinforcing material into the resin helps in retarding the thermal degradation of ...

High α-cellulose has been dissolved in two non-degrading solvent systems like dimethyl sulfoxide/paraformaldehyde (DMSO/PF) and N,N-dimethyl acetamide/lithium chloride (DMAc/LiCl) and then fractionated to different molecular weight fractions by regeneration technique. Esters of the different molecular weight fractions of cellulose have been prepared having substitution chain length of C2-C5 usi...

The thermal degradation of acetaminophen is studied via conventional accelerated aging studies by initially thermally stressing the compound at temperatures between 160 degrees C and 190 degrees C and measuring the rate of decomposition by reversed-phase high-performance liquid chromatography. Rates of decomposition of the compound in the dry state and the activation energy for the process are ...

Information about the thermal degradation of guar gum has been obtained from the time dependence of the viscosity at high temperatures measured using a slit viscometer. The viscosity is related to the molecular weight using previously published relations between the zero shear specific viscosity and the coil overlap parameter in conjunction with the appropriate Mark-Houwink equation. Unlike ani...

This paper gives a first study of the thermal and oxidative ageing ELIUM® resins. Chain ends unzipping was observed to be main degradation mechanism under nitrogen whereas an oxidation with random chain scissions is shown predominate in presence oxygen. A simplified kinetic model proposed fits experimental results for thin films at temperatures ranging from 230 310°C oxygen or nitrogen.