The RHIC coupling correction system has been commissioned during the Year 2000 run, which marked the successful first year of operation of the machine. The RHIC coupling correction system is described with particular emphasis on its flexibility, which allows using both global and local coupling compensation techniques. Coupling measurements and correction data are presented for the RHIC Blue an...

Strain-induced gradients of local electric fields in semiconductor quantum dots can couple to the quadrupole moments of nuclear spins. We develop a theory describing the influence of this quadrupolar coupling on the spin correlators of electron and hole "central" spins localized in such dots. We show that when the quadrupolar coupling strength is comparable to or larger than the hyperfine coupl...

It was recently demonstrated that lugh-resolution deutenum NMR m sohds may be accomphshed by magc angle sample spuming e\ren when the rotation frequency, wJ277 = 1 kHz, IS much less than the quadrupole coupling, WQ/21r = 4 %7-qQ/h = 130 l&I2 [l-4] The sample rotation removes the broademng of spectra of amorphous and polycrystalline samples due to the anlsotropic quadrupole and chemical-shift in...

We report a multinuclear solid-state ( (23)Na, (39)K, (87)Rb, (133)Cs) NMR study of tetraphenylborate salts, M[BPh 4] (M = Na, K, Rb, Cs). These compounds are isostructural in the solid state with the alkali metal ion surrounded by four phenyl groups resulting in strong cation-pi interactions. From analyses of solid-state NMR spectra obtained under stationary and magic-angle spinning (MAS) cond...

Rhenium-185/187 solid-state nuclear magnetic resonance (SSNMR) experiments using NaReO(4) and NH(4)ReO(4) powders provide unambiguous evidence for the existence of high-order quadrupole-induced effects (HOQIE) in SSNMR spectra. Fine structure, not predicted by second-order perturbation theory, has been observed in the (185/187)Re SSNMR spectrum of NaReO(4) at 11.75 T, where the ratio of the Lar...

Density functional theory (DFT) calculations have been performed to study properties of chitosan (Chit) as a possible vehicle for carrying metformin (Met) drug. To this aim, the singular molecules of Met and Chit have been first optimized and sixteen possible bimolecular complexes have been subsequently constructed and optimized to obtaine the stabilized interacting structures. Two bimolecular ...

MP2 calculations with cc-pVTZ basis set were used to analyze intermolecular interactions in F3CX···YLi···NCCN and F3CX···NCCN···LiY triads (X = Cl, Br; Y = CN, NC) which are connected via halogen and lithium bonds. Those complexes with the role of LiY as halogen acceptor and lithium donor show cooperativity with energy values ranging between -1.97 and -2.92 kJ mol...

Density functional theory ,(DFT) calculations have been performed to investigate the properties ofcarbon decorated (C-decorated) models of boron nitride (BN) nanocones. To this aim, the apex andtip of nanocone have been substituted by the carbon atoms to represent the C-decorated models. Theresults indicated that dipole moments and energy gaps could reveal the effects of C-decorations onthe pro...

We investigate the nature of higher-order effects arising in solid-state nuclear magnetic resonance ~NMR! when quadrupolar nuclei are subject to significant chemical shift anisotropies. It is shown that the quadrupole interaction can give rise to shielding-derived terms that are not entirely averaged away by conventional magic-angle spinning ~MAS!. These terms are proportional to the square of ...