نتایج جستجو برای: tri aryl structure
تعداد نتایج: 1593907 فیلتر نتایج به سال:
The crystal structure of the title compound, [Re6Se8{NCC(CH3)3}(Et3P)5](SbF6)2·NCC(CH3)3, contains a face-capped octa-hedral [Re6(μ3-Se)8](2+) cluster core. The pseudo-centrosymmetric [Re6Se8](2+) cluster core is bonded through the Re atoms to five tri-ethyl-phosphane ligands and one tri-methyl-aceto-nitrile ligand. No significant interactions are observed between the cationic cluster, the SbF6...
The single crystal X-ray structure of the DMSO solvate of cyameluric acid C6N7O3H3 · 3DMSO, 2b’ has been determined. The results show that the most stable tautomer of solid cyameluric acid is the tri-keto form 2b with C3h symmetry. 1H and 13C NMR data indicate that this isomer is also present in solution, with slow interchange of the N-H protons. This confirms previous theoretical results altho...
Abstract We report the synthesis of 4‐aryl‐2‐piperidone, 4‐arylpiperidine motifs, antituberculosis molecule Q203 (Telacebec) and its analogues. Direct lactamization β ‐C−H arylated N ‐phthaloyl δ ‐aminopentanoic acid carboxamides yielded 4‐aryl‐2‐piperidone (4‐aryl‐ ‐valerolactam) scaffolds. The required were assembled via Pd(II)‐catalyzed, 8‐aminoquinoline‐aided, sp 3 activation arylation meth...
synthesis of 4-(n,n- dimethylamino)-3-aryl-3-butene-2-one, ethyl-5-aryl-4-oxo-4h-pyran-2-carboxylate, ethyl-5-aryl-4-pyridones-2-carboxylate and 5-aryl-3-cyano-5-methyl-2-pyridones (aryl=3-thienyl, 2-furyl) are described.
New titanium(IV) complexes having two bidentate β-iminoethyl-spiro[4,5]decan-6-onato ligands with various N-aryl substituents have been synthesized. X-ray crystal structure analysis reveals that these titanium complexes all exhibit a C2-symmetric conformation with a distorted octahedral geometry, although the specific orientation of the ligands around the titanium center varies with the identit...
Leishmaniasis is a group of tropical diseases with high worldwide prevalence and difficulty in management. At present, the development of resistance and the increase of co-infected leishmaniasis with AIDS have become a serious public health problem. Thus, designing and discovery of effective and non-toxic drugs for the treatment of this disease is very urgent. Azole derivatives have displayed a...
4-Chlorobenzoate:CoA ligase (CBAL) is a member of a family of adenylate-forming enzymes that catalyze two-step adenylation and thioester-forming reactions. In previous studies, we have provided structural evidence that members of this enzyme family (exemplified by acetyl-CoA synthetase) use a large domain rotation to catalyze the respective partial reactions [A. M. Gulick, V. J. Starai, A. R. H...
The structure of the extracellular polysaccharide (water-insoluble D-glucan) from an anaerobic, Gram-positive coccus organism (Streptococcus) has been investigated. Acid hydrolysis of the methylated glucan yielded 2,3,4,6-tetra-, 2,3,4-tri-, 2,4,6-tri, and 2,4-di-O-methyl-D-glucose in the molar ratios of 1.13:3.99:1.00:1.02, indicating that the D-glucan has a branched structure containing (1 le...
The present review discuss about the structure, reactivity of various amidines. The complexation behavior of amidine especially aryl benzamidine with different metal ions has been discussed. This review article is useful for inorganic and bioinorganic chemist.
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