This essay gives my personal perspective of the current stage computational methods applied to modeling organometallic catalysis, as well new directions field is taking. The first part deals with what I consider state-of-the-art build up energy profiles, regarding both chemical and models. With a proper choice model methods, quantum mechanical calculations are nowadays able provide accurate pro...

the diagnosis of celiac disease (cd) relies on the concordance of pathological, serological, genetic and clinical features. for this reason, the diagnosis of cd is often a challenge. seronegative celiac disease (sncd) is defined by the negativity of anti-tissue transglutaminase antibodies in the presence of a positive histology on duodenal biopsy samples, i. e. inflammatory infiltrate of intra-...