Electrolytes play an integral role in the successful operation of any battery chemistry. The reemergence sodium-ion (SIB) chemistry has therefore rejuvenated search for optimized SIB salts and solvents. Recent experiments have found that 1 M NaPF 6 ethylene carbonate (EC) propylene (PC), EC 0.5 : PC (w/w) is best binary electrolyte SIBs. However, mathematical models, to elucidate these experime...