نتایج جستجو برای: cobalt based catalyst

تعداد نتایج: 2994791  

2017
Andy I. Nguyen Jianing Wang Daniel S. Levine Micah S. Ziegler T. Don Tilley

The oxo-cobalt cubane unit [Co4O4] is of interest as a homogeneous oxygen-evolution reaction (OER) catalyst, and as a functional mimic of heterogeneous cobalt oxide OER catalysts. The synthesis of several new cubanes allows evaluation of redox potentials for the [Co4O4] cluster, which are highly sensitive to the ligand environment and span a remarkable range of 1.42 V. The [Co 4O4] /[Co 3 Co O4...

2017
Xing Zhang Zishan Wu Xiao Zhang Liewu Li Yanyan Li Haomin Xu Xiaoxiao Li Xiaolu Yu Zisheng Zhang Yongye Liang Hailiang Wang

Electrochemical reduction of carbon dioxide with renewable energy is a sustainable way of producing carbon-neutral fuels. However, developing active, selective and stable electrocatalysts is challenging and entails material structure design and tailoring across a range of length scales. Here we report a cobalt-phthalocyanine-based high-performance carbon dioxide reduction electrocatalyst materi...

Although catalyst deactivation rate greatly varies depending on many factors, including the catalyst structure, reactor feed composition, and operating conditions; it is usually inevitable. Since catalyst deactivation modeling has so far been poorly addressed in the literature, in the present study, nine experimental sets of cobalt based Fischer-Tropsch catalysts activity-time data were conside...

Journal: :Catalysis Today 2022

Oxyfuel combustion is a promising technology to produce CO2 rich effluents. Nevertheless, storage as well valorization steps require increase the purity of these effluents due presence CO and NOx produced during process. In view development transition metal-based catalyst for this application, cobalt and/or copper derived hydrotalcite materials were used precursor oxide NO-CO abatement in gas s...

2007
E. N. FRANKEL

Two cobalt-carbonyl oxo processes were developed to prepare useful products in high yield from fatty derivatives. In one process, hydroformylation in the presence of MeOH at 120 C gives dimethyl acetal esters from either methyl oleate or oleic acid. In the other, a two-step process, hydroformylation (120 C) followed by hydrogenation (180 C) gives better yields of hydroxY methyl esters from both...

2013
Zofia Lendzion-Bielun Urszula Narkiewicz Walerian Arabczyk

An effect of promoters such as calcium, aluminium, and potassium oxides and also addition of chromium and manganese on the structure of cobalt catalysts was examined. Studies of the catalytic ammonia decomposition over the cobalt catalysts are presented. The studies of the ammonia decomposition were carried out for various ammonia-hydrogen mixtures in which ammonia concentration varied in the r...

2010
Theerapol Thurakitseree Erik Einarsson Rong Xiang Pei Zhao Shinya Aikawa Shohei Chiashi Junichiro Shiomi Shigeo Maruyama

In this study, we systematically investigated the influence of catalyst preparation procedures on the mean diameter of single-walled carbon nanotubes (SWNTs) synthesized by the alcohol catalytic chemical vapor deposition (ACCVD) process. It was found that the SWNT diameter is dependent upon both reduction temperature and time, with lower reduction temperature and/or shorter reduction time resul...

2010
Corinne Gosmini

Transition metal-catalyzed C–C cross-coupling reactions are among the most powerful transformations known to organic chemists, and have received considerable attention over the last decades. For this reason, the development of mild chemo-, regio-, and stereoselective syntheses for the formation of carbon–carbon bonds catalyzed by metal complexes is of great interest. These methods have had a pr...

Journal: :iranian journal of catalysis 0
negar zekri college of chemistry and chemical engineering, malek-ashtar university of technology, tehran, 16765-3454, i. r. iran. reza fareghi-alamdari college of chemistry and chemical engineering, malek-ashtar university of technology, tehran, 16765-3454, i. r. iran.

a series of copper and cobalt substituted nanospinel ferrites have been synthesized by the hydrothermal method. these compounds were characterized by ft-ir, xrd, edx, sem and vsm techniques. all of the synthesized nanospinel ferrites were found to be highly efficient and magnetically recoverable in the solvent-free synthesis of substituted 2,6-(2-hydroxybenzyl)-phenols (trisphenols). a wide ran...

Journal: :Journal of nanoscience and nanotechnology 2004
Daniel E Resasco José E Herrera Leandro Balzano

Different catalyst formulations and reaction conditions have been used to test the validity of a hypothesis that tries to elucidate the mechanism of single-walled nanotube (SWNT) formation by CO disproportionation over a highly selective cobalt-molybdenum catalyst. This model proposed an intrinsic dependence between the selectivity of the catalysts toward SWNT and the stabilization of Co specie...

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