MARINOVA, G. and V. BATCHVAROV, 2011. Evaluation of the methods for determination of the free radical scavenging activity by DPPH. Bulg. J. Agric. Sci., 17: 11-24 The survey of the methods for determination of free radical scavenging activity by DPPH has been done. The differences between methods conditions and their evaluation are presented. It was determined the effect of methods conditions b...

We developed a detailed chemical kinetics model for the pyrolysis of long-chain polycyclic n-alkylarenes based on a general free-radical mechanism. The model accounts for the two major primary pathways in the pyrolysis network of polycyclic alkylaromatics. Using 1-dodecylpyrene (DDP) as an example, we show that the model qualitatively predicted the effects of time, temperature, and concentratio...

a copolymer of styrene and methyl styrene was synthesized by nitroxide - mediated “living” free radical polymerization )nmp). n-bromosuccinimide was used as a brominating agent to obtain a copolymer with bromine as its end group. this brominated copolymer was used as macro initiators for atom transfer  radical  polymerization  (atrp).  chemical  modifcation  of  the  clay  and transformation of...

In this paper, the synthesis and free-radical scavenging capacity of novel calix[4]arene-based cluster of paracetamol was reported. The phenolic structures of acetaminophen and calix[4]arene prompted us for designing a synthetic route for calix[4]arene-based cyclic tetramer of paracetamol. The present chalice-shaped cluster is the first example of calixarene/acetaminophen hybrid and paracetamol...

In this paper, the synthesis and free-radical scavenging capacity of novel calix[4]arene-based cluster of paracetamol was reported. The phenolic structures of acetaminophen and calix[4]arene prompted us for designing a synthetic route for calix[4]arene-based cyclic tetramer of paracetamol. The present chalice-shaped cluster is the first example of calixarene/acetaminophen hybrid and paracetamol...

The biologically important redox couple, /I-nicotinamide adenine dinucleotide/l,4,/%dihydronicotinamide adenine dinucleotide, provides a grossly reversible prototype system for an overall electrode reaction consisting of two successive one-electron (1 e) transfer steps coupled with (a) dimerization of an intermediate free radical product, (b) protonation-deprotonation of an intermediate product...

The biologically important redox couple, &mcotinarmde adenine dmucIeot~de/l.4.&d~hydromcotinamide adenine dinucleotide, provides a grossly reversible prototype system for an overall electrode reaction consisting of two successive one-electron (1 e) transfer steps coupled with (a) dimenzation of an intcrmtiate free radical product, (b) protonation-deprotonation of an intermediate product, (c) ot...

Background & Aim: Medicinal plants can be a good replacement for common cancer treatment including chemotherapy, radiation therapy and surgery because they don’t have many side effects. The aim of this study was to investigate the effect of temperature on the free radical scavenging in the presence of medicinal plants. Experimental: For determination of free radical scavenging activity was use...

UNLABELLED Measurement of free radical scavenging capacity of antioxidants is influenced by a number of parameters that depend on reaction rate. AIM A new method for assessing the free radical scavenging activity in which the influence of antioxidant concentration and reaction rate on chlorpromazine radical cation absorbance are simultaneously monitored. MATERIALS AND METHODS The change in ...