in this paper, modeling and optimization of fischer-tropsch synthesis is considered in a fixed-bed catalytic reactor using an industrial fe-cu-k catalyst. a one dimensional pseudo-homogenous plug flow model without axial dispersion is developed for converting syngas to heavy hydrocarbons. the effects of temperature, pressure, h2 to co ratio in feed stream, and co molar flow on the mass flow rat...

We describe a nearly explicit chemical mechanism for isoprene photooxidation guided by chamber studies that include time-resolved observation of an extensive suite of volatile compounds. We provide new constraints on the chemistry of the poorly-understood isoprene δ-hydroxy channels, which account for more than one third of the total isoprene carbon flux and a larger fraction of the nitrate yie...

to study the effects of drought stress and foliar application with salicylic acid on yield andit’s components and percentage of essential oil of nigella sativa l., a field experiment was conducted as split plot based on randomized complete block design with three replications at research farm of shahid bahonar university of kerman during growing season of 2013- 2014. the main factor was drought...

The use of alternative fuels in order to reduce the environmental impacts of diesel emissions has been extensively investigated. Trends in the regional use of biomass-derived fuels, such as alcohols, biodiesel and agricultural residues as a proposed control initiative against elevated carbon monoxide levels in urban areas have expanded to a global scale. Waste cooking oil is considered as the m...

BACKGROUND Succinic acid (SA) has become a prominent biobased platform chemical with global production quantities increasing annually. Numerous genetically modified E. coli strains have been developed with the main aim of increasing the SA yield of the organic carbon source. In this study, a promising SA-producing strain, E. coli KJ134 [Biotechnol. Bioeng. 101:881-893, 2008], from the Departmen...

A high-throughput multiparameter optimization of chemical oxidative polymerization conditions has been developed for a facile synthesis of furan homopolymers and furan/aniline copolymers using a combinatorial method. The polymerization yield, molecular structure, and properties of the polymers would be optimized against typical polymerization parameters, including oxidant species, medium specie...

The optical properties of a receptor-targeted probe designed for dual-modality mapping of the sentinel lymph node (SLN) was optimized. Specific fluorescence brightness was used as the design criterion, which was defined as the fluorescence brightness per mole of the contrast agent. Adjusting the molar ratio of the coupling reactants, IRDye 800CW-NHS-ester and tilmanocept, enabled us to control ...

Ah&act-The tem~ratu~-de~ndent thermal expansivities of melts along the join ano~hite-diopside have been determined on glassy and liquid samples using a combination of calorimetry, dilatometry, and Pt double bob Archimedean densitometry. Supercooled liquid volumes and molar thermal expansivities were determined using scanning calorimetric and dilatometric measurements of properties in the glass ...

Chemical synthesis of palm oil trimethylolpropane esters was conducted via transesterification of palm oil methyl esters (POME) with trimethylolpropane (TMP). The palm oil TMP esters are potential biodegradable base stock for lubricant production. The influence of the main operating variables, namely, temperatures and pressures, molar ratio of palm methyl esters to TMP, and catalyst amount was ...

A novel method for linking Adriamycin (ADM) to monoclonal antibodies is described in which the 13-keto position of the anthracycline is used as the attachment site to the linker arm. A new ADM acylhydrazone derivative, Adriamycin 13-[3-(2-pyridyldithio)propionyl]hydrazone hydrochloride, which contains a pyridyl-protected disulfide, was synthesized and used for conjugation to monoclonal antibodi...