ABSTRACT The partition of decay energy between the kinetic energy of reaction products and their Q-value of formation is obtained in a statistical derivation appropriate to highly excited nuclei, and is shown to be in a constant ratio. We measure the kinetic energy fraction, R = ΣEkin/(ΣEkin + ΣQ0), over a wide range of excitation energy for welldefined systems formed in the Cl+C reaction at 35...

The reaction kinetic realizations of nonnegative polynomial systems are studied in this paper. It is brie y reviewed that a wide class of positive systems can be written in or simply transformed to kinetic form. Based on the structure of kinetic realizations, valuable information can be obtained about the dynamical properties of the investigated systems using the results of chemical reaction ne...

The reaction of CH3O2 radicals with acetaldehyde on the solid surface of NH4NO3 has been studied in a flow capillary reactor at low pressure and room temperature. The experiments were performed using EPR spectrometer combined with the kinetic method of radicals freezing. Peroxy radicals revealed an oscillation complex behavior during the process regarding to the phenomenon of radicals multiplic...

A kinetic model of a fixed bed tubular reactor incorporating catalyst deactivation was developed for the ISOMAX unit of Arak refinery. The kinetic parameters for the hydrocracking reactions over the commercial catalyst were determined using initial activity plant data i.e. when the catalyst is fresh. Catalyst deactivation was then taken into account by means of deactivation function based on pl...

the aim of this paper is to study the kinetic study carbonylation of methanol using of the homogeneous rhodium catalyst and ch3i as the promoter in acid media based on monsanto process. the reaction was carried out in liquid media in the constant pressures 20,28 and 40 atm. and temperatures 170 to185oc, espect to the  initial  reactant concentrations and co pressure.  it was identified that the...

Kinetic fluorescence detection (KFD) was employed to determine the concentrations of two overlapped components after a thin-layer chromatographic ("IC) separation. Two amino acids, glycine and glutamine, were used as model analytes. These species exhibited very similar retardation factors (Rf) under our experimental conditions. A reaction that produced a fluorescent product was performed subseq...

The formation of Compounds I, II, and III of hog thyroid peroxidase was demonstrated in its reaction with H2O2 by spectrophotometric and kinetic methods combined with a stopped flow technique. Hog thyroid peroxidase reacted with H2O2 to form Compound I with a rate constant of 5.2 X 10(6) M-1 s-1. Compound I was then spontaneously converted to Compound II with a rate constant of 8 s-1. In the pr...

Experimental studies on the mechanism of copper-catalyzed amination of aryl halides have been undertaken for the coupling of piperidine with iodobenzene using a Cu(I) catalyst and the organic base tetrabutylphosphonium malonate (TBPM). The use of TBPM led to high reactivity and high conversion rates in the coupling reaction, as well as obviating any mass transfer effects. The often commonly emp...

Protein kinase activation, via autophosphorylation of the activation loop, is a common regulatory mechanism in phosphorylation-dependent signaling cascades. Despite the prevalence of this reaction and its importance in biological regulation, the molecular mechanisms of autophosphorylation are poorly understood. In this study, we developed a kinetic approach to distinguish quantitatively between...