Non destructive, real-time monitoring of the stress/strain state of polymer composites can be achieved through a “nanomodification” of the matrix. Due to their high Raman scattering, electrical conductivity and implicit sensitivity to pressure and temperature, single-walled carbon nanotubes (SWCNT) are ideal elements to fulfil this task. In this work, SWCNT at a loading fraction as low as 0.1 w...

The network build-up process during curing of an epoxy resin using a hyperbranched poly(ethyleneimine) as crosslinking agent has been studied from a theoretical and experimental point of view. A systematic analysis taking into account the stoichiometry of the curing process has been performed. Conversion at gelation has been studied by thermomechanical analysis (TMA) and differential scanning c...

OBJECTIVES The aim of this in vitro study was to evaluate the influence of different light curing units and modes on microleakage of flowable composite resins. METHODS Eighty Class V cavities were prepared in buccal and lingual surfaces of 40 extracted human premolars with cervical wall located in dentin and the occlusal wall in enamel. These teeth were randomly assigned into two groups (n=20...

This paper investigates application of piezoelectric ceramics mounted on surface of mould to monitor flow front and curing phases of resin in Resin Transfer Moulding (RTM) process. The piezoelectric ceramic is used for both generating ultrasound and measuring energy of echoed ultrasonic wave at the interface of mould and resin. One of the advantages of this method is that the piezoelectric cera...

The Bayer process utilises high concentrations of caustic and elevated temperature to liberate alumina from bauxite, for the production of aluminium and other chemicals. Within Australia, this process results in 40 million tonnes of mineral residues (Red mud) each year. Over the same period, the energy production sector will produce 14 million tonnes of coal combustion products (Fly ash). Both ...

afinite element model is developed for simulation of the curing process of a thick axisymmetric rubber article reinforced by metal plates during the molding and cooling stages. the model consists of the heat transfer equation and a newly developed kinetics model for the determination of the state of cure in the rubber. the latter is based on the modification of the well-known kamal-sourour mode...

The thermal conductivity of the diglycidyl ethers bisphenol-A (DGEBA)/4,4′-diaminodiphenylmethane (DDM)/polyethersulphone (PES)/silver (Ag) filler composites has been investigated. DGEBA/DDM/PES blend as matrix for polymer formed co-continuous phase structures at micrometer scale via reaction-induced separation during curing process. Ag fillers were selectively localized in epoxy-rich phases, a...

We consider the propagation of a contagion process (“epidemic”) on a network and study the problem of dynamically allocating a fixed curing budget to the nodes of the graph, at each time instant. For bounded degree graphs, we provide a lower bound on the expected time to extinction under any such dynamic allocation policy, in terms of a combinatorial quantity that we call the resistance of the ...

The use of electrically conductive adhesives as interconnection materials in electronic assembly process is increasingly becoming a vital part of the electronics industry. Flip-chip joining technique using conductive adhesives has been identi®ed as a key technology for future electronics assembly and manufacturing. The purpose of the present work is to investigate optimum conditions to achieve ...