Two new 1,8-naphthalimides (NI), emitting yellow-green or blue fluorescence depending on the type of substituents at C-4 position, have been synthesized and characterized. Their basic photophysical characteristics investigated in organic solvents different polarities. ability to detect metal ions (Ag+, Cu2+, Zn2+ Ca2+, Mg2+, Ni2+, Fe3+) has studied DMF solution. The amino (NI1) alkoxy (NI2) fun...

The first chalcone-based colorimetric chemosensor DPP (sodium (E)-2,4-dichloro-6-(3-oxo-3-(pyridine-2-yl)prop-1-en-1-yl)phenolate) was synthesized for detecting Ni2+ in near-perfect water. synthesis of validated by using 1H, 13C NMR and ESI-MS. selectively sensed through the color variation from yellow to purple. Detection limit calculated be 0.36 μM (3σ/slope), which is below standard (1.2 μM)...

A time-dependent inhibition of the thyrotropin-releasing-hormone (TRH)-degrading ectoenzyme (EC 3.4.19.-) from rat brain by the metal-complexing agents imidazole, NaCN, EDTA and 1,10-phenanthroline could be demonstrated. In contrast, the inhibition by the non-chelating analogues 4,7and 1,7-phenanthroline was not time-dependent. At a concentration of 100 ,M EDTA the enzymic activity decreased by...

The antimonato-polyoxovanadate {NiII(en)3}3[VSbO42(H2O)]·ca.15H2O was utilized as a synthon for the solvothermal in situ generation of the new compound {NiII(phen)3}2[{NiII(en)2}VSbO42(H2O)]·19H2O, a rearrangement induced by ligand metathesis. While in the precursor structure cations and anions are isolated, the solid-state structure of the product is characterized by 1D chains consisting of al...

Properties of solid phases formed during the oxidation of EDTA by permanganate in a high-pH, high-ionic strength solution, and the retention of Cu2+, Ni2+, and Zn2+ by them were examined. Morphologically, the solids were agglomerates of particles with sizes <100 nm. X-ray absorption spectroscopy (XAS) analysis indicated that these particles were birnessite. Its precipitation was accompanied by ...

The uptake of Cu2+ was investigated using various types of liposomes composed of phosphatidylcholine (PC), cholesterol (Chol) and dicethylphosphate (DCP). DCP played a role as a ligand for Cu2+. Multilamellar vesicles (MLVs) were more effective for the uptake of Cu2+ compared to unilamellar vesicles prepared by the extrusion technique. The uptake efficiency of MLVs for Cu2+ was dependent on the...

The significant shift in kinetic and equilibrium behavior of complex formation between Ni2 and 2-amino-cycloŽ . Ž . pentene-1-dithiocarboxylic acid ACDA in a solution of ionic surfactant cetyltrimethylammonium bromide CTAB was studied spectrophotometrically in 0.1 M NaBr medium at 30 C. A model based on distributions of ligand Ž . Ž . ACDA and complex Ni ACDA between aqueous and micellar pseudo...

Ni2+, Fe2+ and Cu2+ were attractants and aspartate was an apparent repellent for Leptospirillum ferrooxidans, a behaviour opposite to that for Escherichia coli. Membranes from L. ferrooxidans contained proteins with a molecular mass in the range of 80 kDa which were methylated in vitro. Methylation was stimulated in the presence of a membrane-free extract from E. coli, showing the response patt...

A novel lignosilicate (LS) composite was synthesized from pre-extracted (hot water, 80% ethanol, 0.3 N NaOH) lignin of rice husk (RH) using TEOS as matrix. The extracted lignins were subjected to surface modification by acetylation followed by in situ synthesis of lignosilicate (LS) composites by sol-gel method for application in nickel removal. LS were characterized by FT-IR, scanning electron...