Thermodynamic analysis of a novel combined system which is combination of methane fired gas turbine cogeneration system (CGAM) with a supercritical CO2 recompression Brayton cycle (SCO2) and an Organic Rankine Cycle (ORC) is reported. Also, a comprehensive parametric study is performed to investigate the effects on the performance of the proposed system of some important parameters. Finally, a ...

Binding of ligands, ranging from proteins to ions, to membrane proteins is associated with absorption or release of heat that can be detected by isothermal titration calorimetry (ITC). Such measurements not only provide binding affinities but also afford direct access to thermodynamic parameters of binding--enthalpy, entropy and heat capacity. These parameters can be interpreted in a structural...

abstractin this work, the micro powder was the product of cedar leaf (mpcl) is used as a low-cost adsorbent for the removal of pb2+ ions from aqueous solutions. bath experiments were used to determine the best adsorption conditions the adsorption percentage of pb2+ ions mpcl samples at different initial ph, contact time (tc), adsorbent dosage and temperature (t) were investigated. effective rem...

Description of the recognition specificity between proteins and nucleic acids at the level of molecular interactions is one of the most challenging tasks in biophysics. It is key to understanding the course and control of gene expression and to the application of the thus acquired knowledge in chemotherapy. This review presents experimental results of thermodynamic studies and a discussion of t...

Packaging of genetic material inside a capsid is one of the major processes in the lifecycle of bacteriophages. To establish the basic principles of packing double-stranded DNA into a phage, we present a low-resolution model of bacteriophage varphi29 and report simulations of DNA packaging. The simulations show excellent agreement with available experimental data, including the forces of packag...

The thermodynamic of the known and very effective catalytic system, hydrogen peroxide (H2O2) and methyltrioxorhenium (MTO) is studied in different solvents using UV-Visible spectroscopic method. The thermodynamic parameters (ΔG, ΔH and ΔS) for two equilibrium reactions, MTO + H2O2 ⇌ A + H2O and A + H2O2 ⇌ B.H2O (A, [MeRe(O)2(O2)]; B.H2O, [MeRe(OH2)(O)(O2)2]), are determined. The obtained free e...

Recently, Cong et al. (2010) published a comprehensive study on the characterization of reductive properties of hexachlorocyclohexanes (HCHs) and dichlorodiphenyltrichloroethane (DDTs) using powdered metallic iron (Fe). Quantum chemical descriptors characterizing different molecular structures and physicochemical properties of the seven tested organochlorine pesticides (4 HCHs and 3 DDTs) were ...