Fluid catalytic cracking (FCC) is a major process in oil refineries to produce gasoline and base chemicals from crude oil fractions. The spatial distribution and acidity of zeolite aggregates embedded within the 50-150 μm-sized FCC spheres heavily influence their catalytic performance. Single-molecule fluorescence-based imaging methods, namely nanometer accuracy by stochastic chemical reactions...

Comparative studies over micro-/mesoporous Cu-containing zeolites ZSM-5 prepared by top-down treatment involving NaOH, TPAOH or mixture of NaOH/TPAOH (tetrapropylammonium hydroxide) were conducted. The results the catalytic data revealed highest activity Cu-ZSM-5 catalyst both in absence and presence water vapor. physico-chemical characterization (diffuse reflectance UV-Vis (DR UV-Vis), Fourier...

This work describes the optical and structure properties of nickel sulfide and cobalt sulfide nanoparticles in ZSM-5 zeolite. The samples were obtained by sulfidation of the Ni2+ and Co2+ ion-exchange ZSM-5 zeolites in a Na2S solution at room temperature. The optical properties of the samples were studied by UV-visible spectroscopy. Their crystalline structure and morphology were studied by X-r...

Nano-sized protonated ZSM–5 ( H-ZSM-5nanozeolite) was successfully synthesized by the hydrothermal method using the bagasse ash (BGA) as a new silica source. Cultivated BGA in the south of the Caspian Sea (Mazandaran province, Iran) was used for extracting silica powder. H-ZSM-5 was characterized by Fourier transform infrared (FT-IR), X-ray diffraction (XRD), scanning electronic microscopy (SEM...

this work describes the optical and structure properties of nickel sulfide and cobalt sulfide nanoparticles in zsm-5 zeolite. the samples were obtained by sulfidation of the ni2+ and co2+ ion-exchange zsm-5 zeolites in a na2s solution at room temperature. the optical properties of the samples were studied by uv-visible spectroscopy. their crystalline structure and morphology were studied by x-r...

This study developed an upgrading process focusing on acid transformations of water phase pyrolysis bio-oils to esters of oxygen-containing fuels via ZSM−5 catalyst. Temperature was set as a factor with five levels ranging from 60 to 135 °C with reaction time from 1 to 8 h. The results showed that 89% of high acid conversion and over 90% of ester selectivity was obtained from the feedstock via ...

Platinum metal was dispersed on microporous, mesoporous, and nonporous support materials including the zeolites Na-Y, Ba-Y, Ferrierite, ZSM-22, ETS-10, and AIPO-11, alumina, and titania. The oxidation of carbon black loosely mixed with catalyst powder was monitored gravimetrically in a gas stream containing nitric oxide, oxygen, and water. The carbon oxidation activity of the catalysts was foun...

The purpose of this work is to develop a low-cost and high-performance catalyst for the selective catalytic hydrogenation acetylene ethylene. Non-precious metals Cu Ni were selected as active ingredients study. Using ZSM-12 carrier, Cu-Ni bimetallic catalysts CuNix/ZSM-12 (x = 5, 7, 9, 11) with different Ni/Cu ratios prepared by incipient wetness impregnation method. total loading 2 wt%. Under ...

LaMnO3 and LaMnO3/ZSM-5 nano catalysts were synthesized by Pechini method and their physical-chemical properties were characterized using XRD, FTIR, SEM-EDX, UV-vis DRS, BET surface area and TPR. The correlation between characteristic properties and activity of catalysts were investigated. The catalytic performance of the catalysts was evaluated in combustion of 2-propanol...

Vanadium silicates such as V-Al-analcime, V-analcime, V-magediite and V-ZSM-11 were synthesized using vanadium pentoxide or vanadyl sulfates. Vanadium silicates with analcime structure with and without aluminum (V-Al-analcime, V-analcime) were prepared as pure phase by hydrothermal crystallization from a gel with molar composition of (1 SiO2; 0.2 V2O5; 1 Na2O; 0.034 Al2O3; 35.7 H2O) and (1 SiO2...