an extensive study of fischer-tropsch synthesis (fts) on alumina-supported cobalt catalysts with different amounts of cobalt is reported. up to 40 wt % of cobalt, is added to the catalysts by impregnation method. the effect of the cobalt loading on the reducibility of the cobalt oxide species, dispersion of the cobalt, average clusters size, water-gas shift (wgs) activity and activity and selec...

A series of Fe3O4 supported on mesoporous FDU-12 silica systems were prepared by the hydrothermal conditions. The surface properties of the functionalized catalyst were analyzed by a series of characterization techniques like FTIR, XRD, N2 adsorption–desorption and TEM. XRD and adsorption–desorption analysis shows that the mesostructure of FDU silica remains intact after Fe3O4 modifications, wh...

The reaction kinetics of the isomerization 3,4-dichlorobutene-1 to 1,4-dichlorobutene-2 was investigated by using gas-liquid chromatography method in the presence of Fe2O3/MgO as solid catalyst in the temperature range 25-55°C. Fe2O3/MgO has been prepared by the support saturation method, tested in the isomerization of 3, 4-dichlorobutene-1 into 1, 4-dichlorobutene-2. This catalyst shows a high...

The super-Brownian motion X % in a super-Brownian medium % constructed in DF96a] is known to be persistent (no loss of expected mass in the longtime behaviour) in dimensions one ((DF96a]) and three ((DF96b]). Here we ll the gap in showing that persistence holds also in the critical dimension two. The key to this result is that in any dimension (d 3); given the catalyst, the variance of the proc...

background marine sponge/nano-cuo as a natural catalyst efficiently catalyzed the sulfonylation reaction of p-chlorobenzene sulfonyl chlorides with amines in order to prepare sulfonamides. the advantages included use of a natural catalyst, ease of handling, requirement of a very small amount of catalyst, mild reaction condition and appropriateness to high yield. objectives the current study aim...

Submitted: Jul 11, 2013; Accepted: Aug 9, 2013; Published: Aug 25, 2013 Abstract: The method of power-efficient two-stage dehydrogenation of isopentane to isoprene considered in this study comprises the production of a mixture of isoamylene at the first stage, further dehydrogenation of which occurs with a smaller endothermal effect. The effectiveness of the proposed method for energy saving is...

Metalloporhyrin ligand, [tetrakis(o-chlorophenyl)porphyrinato]Ni(II) was successfully immobilised onto inorganic silica support from rice husk ash via 3-aminoprorplytriethoxysilane (APTES) and the resulting catalyst was labeled RHACNiPor. This mesoporous organic-inorganic hybrid catalyst showed a high specific surface area of 190.0 m g. The Si MAS NMR solid-state spectrum showed the presence of...

Synthesize carbon-based metal-free catalysts and • carbon-composite catalysts for oxygen reduction reaction (ORR). Optimize catalytic active reaction sites as a function • of carbon support, surface oxygen groups, nitrogen content, surface modifiers, pyrolysis temperature, porosity, and the concentration of the non-metallic additive “X” in the catalyst matrix. Evaluate catalyst stability under ...

The immobilization of the catalyst on a support with the aim of facilitating the separation of the product from the catalyst, and thus the recovery and recycling of the latter, can be regarded as an important improvement for a catalytic process. However, a system where a catalyst must not be removed from the reaction vessel is even more attractive: in continuous flow methods the immobilized cat...