Nanocrystalline (nc) materials can be defined as solids with grain sizes in the range of 1–100 nm. Contrary to coarse-grained metals, which become more difficult to twin with decreasing grain size, nanocrystalline face-centered-cubic (fcc) metals become easier to twin with decreasing grain size, reaching a maximum twinning probability, and then become more difficult to twin when the grain size ...

A mechanism of the transport of nanocrystalline doped calcium carbonatephosphates through the membrane on the model of interaction with phospholipids is considered. Nanocrystalline doped calcium carbonate – phosphates are perspective to transport of the cations in a living cell. Kinetics of the synthesis of nanocrystalline doped calcium carbonatephosphates are non-linear kinetics. Biomaterial b...

The compositions and molecular structures of anhydrous and hydrated cements are established by using advanced solid-state nuclear magnetic resonance (NMR) spectroscopy methods to distinguish among different molecular species and changes that occur as a result of cement hydration and setting. One- and two-dimensional (2D) solid-state (29)Si and (27)Al magic-angle spinning NMR methodologies, incl...

In this paper, the performance of the cutting tool with nanocrystalline multilayer coatings (TiN+TiAlN) for machining of superalloy Inconel 718 in the dry and wet conditions was studied. The multi layer TiN and TiAlN with nanocrystalline structure was applied by physical vapor deposition technique (arc evaporation) on the WC-Co inserts. The results of the ball on disc wear test and the machinin...

Nanocrystalline cerium oxide is an attractive material for catalysis of environmentally hazardous gas-phase species such as sulfur dioxide and carbon monoxide. Oxygen vacancies in cerium oxide are believed to coordinate and aid in the transfer of oxygen ions between the reactive species. We have sought to characterize these defects in nanocrystalline cerium oxide as a function of the heat treat...

Nanoparticles of strontium aluminate phosphors co-a tivated by Eu2+ and Dy3+ have been prepared by heating theprecursorsobtained fromnitrate salt–ammoniumacetic–urea–gel combustionprocess at temperature of 1150 ◦C in a weak reductive atmosphere of thermal carbon. Transmission electronmicroscope

The effect of pseudowollastonite (Pw) additions on the in vitro bioactivity and compressive strength of composites based on calcium aluminate cement (CAC) was studied. Composites were prepared by mixing calcium aluminate clinker with pseudowollastonite (5 and 10 wt%) at a w/c ratio of 0.4 (0.015M LiCl aqueous solution). In order to assess the in vitro bioactivity and compressive strength, compo...

A basic alumina-spinel low cement castable (LCC) composed of sintered bauxite, reactive alumina, calcined alumina, calcined magnesia, microsilica, and high alumina refractory cement was prepared (castable A) to which 5% sodium hexa-meta phosphate was later added (castable B) to prepare samples for heat treatment at 110ºC, 900ºC, and 1400ºC. Bulk Density (BD), Apparent Porosity (AP), and Cold Cr...

Atom-resolved non-contact atomic force microscopy (NC-AFM) studies of the magnesium aluminate (MgAl(2)O(4)) surface have revealed that, contrary to expectations, the (100) surface is terminated by an aluminum and oxygen layer. Theoretical studies have suggested that hydrogen plays a strong role in stabilizing this surface through the formation of surface hydroxyl groups, but the previous studie...