QCT calculations were performed to study the behavior of energized NH2OH formed by association collision of NH2 radical with OH radical. A potential energy surface that describes the behavior of the title reaction has been constructed by interpolation of ab initio data. H2O, HON, HNO, NH3, O, H2NO, cis or trans-HONH, and H products and two vibrationally energized NH2OH and NH3O adducts were obs...

The initial events after photoexcitation and photoionization of α-tocopherol (vitamin E) and the analogue Trolox C have been studied by femtosecond stimulated Raman spectroscopy, transient absorption spectroscopy and time-resolved infrared spectroscopy. Using these techniques it was possible to follow the formation and decay of the excited state, neutral and radical cation radicals and the hydr...

The antioxidant activity, contents of total phenolics and flavonoids were quantified in the methanolic extracts of four Ulva species(U.clathrata,U.linza,U.flexuosa and U.intestinalis) grown at different parts of northern coasts of the Persian Gulf in south of Iran.The seaweeds were collected from Dayyer,Taheri and Northern Ouli coasts in April 2011. Methanolic extracts of the seaweeds were asse...

It has been recently shown that radical-ion pairs and their reactions are a paradigm biological system manifesting non-trivial quantum effects, so far invisible due to the phenomenological description of radical-ion-pair reactions used until now. We here use the quantum-mechanically consistent master equation describing magnetic-sensitive radical-ion-pair reactions to explain experimental data ...

conclusions psa, psa density, and gleason score should be considered together in order to more accurately predict the adverse pathologic features of prostate cancer. methods we conducted a cross-sectional study of 105 patients with localized prostate cancer who underwent radical prostatectomy between 2006 and 2013. we recorded gleason scores and psa levels, in addition to the results of patholo...

Robotic radical prostatectomy is now the gold standard for patients with localised prostate cancer. In the setting of unfavourable prostate pathology, some men may require resection of one or both cavernous nerves at the time of prostatectomy. Potency rates in this subset of men are expectedly dismal [1]. With increasing numbers of younger men being diagnosed with prostate cancer and subsequent...

costus speciosus (koen) j.e. sm. plant and its extracts are used for treatment of fever, snake bites, jaundice, and as a purgative, astringent and antibacterial agent. in the present study, an attempt has been made to evaluate in vitro antioxidant activity of different extracts of this plant by dpph radical scavenging activity, total antioxidant capacity, nitric oxide scavenging activity, ion c...

Recently, self-healing polymers based on disulfide compounds have gained attention due to the versatile chemistry of disulfide bonds and easy implementation into polymeric materials. However, the underlying mechanisms of disulfide exchange which induce the self-healing effect in poly(disulfide)s remain unclear. In this work, we elucidate the process of disulfide exchange using a variety of spec...