During a study of catalytic hydrodesulphurization of gas oils’ a method was needed not only for the determination of the distribution of sulphur compounds, but also, more importantly, for the determination of total suIphur content. Methods have been published for the determination of the distribution of sulpbur compounds in gas oils using gas chromatography (GC) with a coulometric detector’>3. ...

the electrocatalytic oxidation of captopril (cap) was studied by modified carbon nanotubes paste electrode in the presence of isoproterenol (ispt) using cyclic voltammetry (cv), chronoamperometry and square wave voltammetry (swv). also, the values of catalytic rate constant (k), and electron transfer coefficient (α) for cap were calculated. the mechanism of ca electrochemical behavior at the mo...

A sensitive and selective kinetic-spectrophotometric method was developed for the determination of trace amounts of uric acid. The method is based on the inhibitory effect of uric acid on the oxidation of Janus Green by bromate in the presence of sulfuric acid. The reaction was followed spectrophotometrically by measuring the absorbance at 518 nm using the fixed-time method. Under optimum exper...

in the present study, silver oxyfluoride modified silver electrode was employed to electrocatalytic oxidation of isoniazid. the process of oxidation and its kinetics were established by using cyclic voltammetry, chronoamperometry and amperometry techniques. the modified electrode shows a stable and linear response in the concentration range of 3×10−4 to 2.1×10−3 mol l-1 with a correlation coeff...

In order to overcome the instability of natural glutathione peroxidase (GPx), scientists endeavor to produce GPx mimics. The popular method first uses biological imprinting (BI) to produce the substrate binding sites and then employs chemical mutation (CM) to obtain the catalytic site. However, BICM has a drawback in that the catalytic site is not clear. Some researchers therefore tried to chan...

a sensitive and selective kinetic-spectrophotometric method was developed for the determination of trace amounts of uric acid. the method is based on the inhibitory effect of uric acid on the oxidation of janus green by bromate in the presence of sulfuric acid. the reaction was followed spectrophotometrically by measuring the absorbance at 518 nm using the fixed-time method. under optimum exper...