:Picloram (4.amino-3,5,6-trichloropicolinic acid) is a ‘herbicide used for the control of woody and broadileaf plants and is marketed by the Dow Chemical .Companyi in formulations bearing the trade name Tordon@. Many agriculturally-impel-tant broadleaf ‘crops are susceptible lo very low levels of pi&ram lI@ab 1975: Thomson 1978). The potassium salt of picloram is very soluble in water and is sl...

Lead forms the complexes with xylenol orange in the basic solution. An adsorptivedifferential pulse stripping method for the determination of lead is proposed. The procedureinvolves an adsorptive accumulation of lead on a hanging mercury drop electrode (HMDE) inthe presence of xylenol orange, followed by reduction of adsorbed lead by voltammetric scanusing differential pulse modulation. The opt...

been investigated using polarography, cyclic voltammetry, coulometry, a n d product analysis. TPP proceeds by a one-electron transfer to form the anion radical which undergoes cleavage of a phenyl group. The electrochemical reduction of triphenylphosphine (TPP) and triphenylphosphine oxide (TPPO) has The reduction of everal recent papers have been concerned with the S polarography of triphenylp...

This communication characterises the differential pulse voltammetric response of ultramicroelectrodes in connection with two different models.

Developments in chromato-polarography and the results obtained from its application to the analysis of mixtures of organic compounds are presented. The possibility of determining traces of organic impurities in organic substances by this technique is evaluated. The polarographic method is today one of the most important instrumental methods and has found wide application in analytical chemistry...

Helix-coil transition of poly aspartic acid (PASP) was investigated by dc polarography in the presence of Cd2+ and/or Zn2+ as a detecting marker which attached to the polymer. The diffusion currents (id) of Cd2+ and Zn2+ decreased sharply in the pH range of 3.5-7.0 due to the formation of the metal ions-PASP macromolecular complexes. The complex formation revealed on an increase in the magnitud...

In recent years, a series of thiamine derivatives has been synthesized and many investigations have been made both chemically and medically. Allithiamine, a S-alkyl thiamine derivative, was studied in the previous pa per (1) and was found to have polarographically a similar behavior to thia mine. In the present experiment, polarographic investigations on diacetyl thiamine (DAT) and dibenzoylthi...