Abstract Acidic biotrickling filters (BTF) can be used for simultaneous removal of hydrogen sulfide (H2S) and siloxane from biogas. In this study, the performance a BTF under different acidic pH conditions was investigated. The profile H2S showed that 90% achieved during first 0.4 m height with down-flow Decamethylcyclopentasiloxane (D5) decreased 34.5% to 15.6% when increased 0.88 3.98. Furthe...

a simple and mild procedure for the conversion of anilines into aryl isocyanates is described using the 3-hydroxypropylammonium acetate (hpaa) ionic liquid as a novel and efficient media has been explored in the synthesis of aryl isocyanates from the reaction of substituted urea with sodium nitrite in a water immiscible solvent. this ionic liquid can be easily recovered and reused for many time...

A study was undertaken of the solvolysis of pivaloyl triflate in a variety of ionic liquid:alcohol solvent mixtures. The solvolysis is a kΔ process (i.e., a process in which ionization occurs with rearrangement), and the resulting rearranged carbocation intermediate reacts with the alcohol cosolvent via two competing pathways: nucleophilic attack or elimination of a proton. Five different ionic...

in this work, the efficiency, generality and applicability of new bronsted acidic ionic liquid (bail) 1-methyl-3-(2-(sulfooxy)ethyl)-1h-imidazol-3-ium chloride {[msei]cl} as heterogeneous and green catalyst for organic transformations are studied. herein, the following one-pot multi-component reactions in the presence of [msei]cl are investigated: (i) the synthesis of quinoxaline derivatives fr...

Transparent, flexible, self-standing and highly ion conductive ion gels have been synthesised from novel ionic liquid compatible cyclic carbonate (CC) network polymer. The use of dual functional cyclic carbonate methacrylate (CCMA) monomer for the synthesis has enabled versatile and operationally simple routes to such type of ion gels.

1-butyl-3-methyl imidazolinium hydroxide ionic liquid (BMIm[OH]) is loaded on commercial low surface area Pd-Ag/α-Al2O3 solid ‎catalyst to enhance higher selectivity of acetylene partial hydrogenation. Different experimental techniques such as atomic absorption spectroscopy, surface area measurement and gas chromatography have been utilized to characterize chemical, structural and catalytic pro...

The application of ionic liquids as environmentally benign reaction solvents for synthesis and catalysis has received extensive recent attention. In this regard we have developed ionic liquids based on the cheap and readily available components choline chloride (ChCl; HOCH2CH2N(Me)3?Cl) and zinc chloride as alternatives to the more commonly employed alkyl imidazolium-aluminium chloride mixtures...

The density (d), speed of sound (u) and electrolytic conductivity (Λ) for systems containing acetaminophen, ionic liquid {1-octyl-3-methyl imidazolium bromide, [OMIm] Br} and water have been measured at T = 293.15-308.15 K. The measured data have been applied to calculate, standard partial molar volume ( ), Hepler’s constant , apparent molar isentropic compressibility...