The efficiency of HZSM-5 Zeolite, tungestophosphoric acid (H3PW12O40) and tungestosililic acid (H4O40SiW12) were investigated in three-component, one-pot synthesis of coumarin dyes. These green and noncorrosive acids were highly efficient in synthesis of some coumarin dyes in excellent yield during concurrent formation of coumarin and benzimidazole or benzoxazole heterocycles (e.g. C. I. disper...

The asymmetric unit of the title compound, C(10)H(12)N(2)O(3)·2H(2)O, contains two organic mol-ecules with similar conformations and four water mol-ecules. Each organic mol-ecule is close to planar (r.m.s. deviations = 0.035 and 0.108 Å) and adopts a trans conformation with respect to its C=N bond. In the crystal, the components are linked into a three-dimensional network by N-H⋯O, O-H⋯O, O-H⋯N...

organic acids exuded by plant roots increase solubility of soil micronutrient complexes. this study was carried out to evaluate adsorption isotherms of 4 acidic and 4 calcareous soils at presence of organic acids (citric, malic and oxalic acids). iron sorption and desorption isotherms are defined in to two systems including; system 1; soil-water-metal, system 2; soil-water-organic acid-metal). ...

Understanding how nutrients affect gene expression will help us to understand the mechanisms controlling plant growth and development as a function of nutrient availability. Nitrate has been shown to serve as a signal for the control of gene expression in Arabidopsis. There is also evidence, on a gene-by-gene basis, that downstream products of nitrogen (N) assimilation such as glutamate (Glu) o...

Allison, C.W. and Awramik, S.M., 1989. Organic-walled microfossils from earliest Cambrian or latest Proterozoic Tindir Group rocks, northwest Canada. Precambrian Res., 43: 253-294. Uppermost Tindir Group limestones exposed in the headwaters of Tindir Creek, Yukon Territory, Canada, contain a diverse and abundant microbiota of mineralized and organic-walled microfossils. Preserved primarily in c...

The mineralization/immobilization of nitrogen when organic sources are added to soil is represented in many simulation models as the outcome of decomposition of the added material and synthesis of soil organic matter. These models are able to capture the pattern of N release that is attributable to the N concentration of plant materials, or more generally the C:N ratio of the organic input. How...

In blackwater river estuaries, a large portion of external carbon, nitrogen, and phosphorus load are combined in complex organic molecules of varying recalcitrance. Determining their lability is essential to establishing the relationship between anthropogenic loads and eutrophication. A method is proposed in which organic C, N, and P are partitioned into labile and refractory forms, based upon ...

Microbial nitrogen use efficiency (NUE) describes the partitioning of organic N taken up between growth and the release of inorganic N to the environment (that is, N mineralization), and is thus central to our understanding of N cycling. Here we report empirical evidence that microbial decomposer communities in soil and plant litter regulate their NUE. We find that microbes retain most immobili...

Nonvolatile organic field-effect transistor (OFET) memory devices based on pentacene/N,N'-ditridecylperylene-3,4,9,10-tetracarboxylic diimide (P13)/pentacene trilayer organic heterostructures have been proposed. The discontinuous n-type P13 embedded in p-type pentacene layers can not only provide electrons in the semiconductor layer that facilitates electron trapping process; it also works as c...

being an environment friendly and more sustainable farming system. Ironically, scientists one-half century Groundwater has become increasingly degraded by NO3, and this ago devoted much research emphasis to providing farmdegradation has been partially attributed to the use of commercial inorganic N fertilizers. Conversion from conventional fertilizer maners information on the beneficial use of ...