فرحناز نورمحمدیان
گروه پژوهشی مواد رنگزای آلی، موسسه پژوهشی علوم و فناوری رنگ و پوشش
[ 1 ] - ارتباط رنگ و ساختار مواد رنگزای آلی: مروری بر بیش از یک قرن پژوهش
ارتباط بین رنگ و ساختار ملکولی مواد رنگزای آلی برای مدت طولانی، موضوعی بسیار مورد علاقه هم برای شیمیدانان مشغول در زمینه ترکیبات آلی و هم شیمیدانان تئوریسین بوده است. به دلیل اهمیت این موضوع، از زمان ارائه اولین تئوری در مورد گروه-های کروموفور و آگزوکروم توسط آقای ویت تقریباً بیش از یک قرنِ پیش تعداد زیادی از مقالات در مورد این مطلب در نشریات علمی چاپ گردیده است. پیدایش نظریه کوانتوم تا حد زیا...
[ 2 ] - بررسی اثر رنگ دهی و شارژپذیری رنگدانه های مورد استفاده در تونرهای الکتروفتوگرافی
از آنجا که امروزه استفاده از فناوری چاپ و کپی برداری به روش الکترو فوتوگرافی به طور فزاینده ای در حال رشد است، مرکب مورد استفاده در این نوع فناوری که اصطلاحاً به آن تونر گفته می شود ،نیز مورد توجه فراوان محققین قرار گرفته است. تا چندی پیش فقط نسخه های چاپی سیاه و سفید در دسترس عموم بوده است و این در حالیست که نسخه های رنگی برای کاربران بسیار جذاب تر و دارای اهمیت بیشتری هستند. رنگدانه ها و رنگین...
[ 3 ] - Photophysical Responses of Benzimidazolic and Benzoxazolic HydroxyCoumarin Dyes
We synthesized four novel benzoxazolic and benzimidazolic derivatives of 6-hydroxycoumarin and their photophysical properties were studied. The products with brilliant yellow color shades declared green fluorescence. The emission peaks of the products appeared 456–474 nm. The important characteristic for fluorescent compounds, the Stokes shift νA-νF, oscillator strength f, and fluorescence quan...
[ 4 ] - Mixture of Ionic Liquids as Novel Media for Green Synthesis of Diketopyrrolopyrrole Pigments
A green method for the synthesis of high-performance diketopyrrolopyrrole pigments using diethyl succinate in the presence of mixture of ionic liquids is reported. Although, alkaline condition is needed in the succinate ester route for synthesis of the pigments, in the present study, the replacement possibility of conventional organic base by mixture of BMIMOH and BMIMBF4 ionic liquids was inve...
[ 5 ] - Novel Aza-Substituted Benzothiazol and 1,2,4-Triazol Cyanine Dyes: Synthesis, Characterization and Properties
Series of novel dichromophoric cyanine dyes based on 2-aminobenzothiazoles and 3-amino-1,2,4 -triazole have been synthesized in high yields. All the dyes have been classified as disperse dyes. Besides their electronic spectroscopic properties, high dye-uptakes on polyester, excellent fastness properties, highly extinction coefficients, and broad solvatochromic effects have been observed in thes...
[ 6 ] - Crystal Phase Study of Pigment Red 254 in the Presence of Ionic Liquids
Different crystal phase with a same chemical structure, polymorphous, is a specific physical characteristic which determine the end usage of pigments especially in high performance ones. Diketopyrrolopyrrole DPP derivatives, as one of the innovative in heterocyclic pigments, follow this pattern. Synthesis of pigment red 254 in selected crystal phase using ionic liquids was achieved without any ...
[ 7 ] - Application of synthesized nanoscale zero-valent iron in the treatment of dye solution containing Basic Yellow 28
Nanoscale zero-valent iron NZVI particles were synthesized by the aqueous phase borohydride reduction method, and the synthesized NZVI particles were used for the degradation of Basic Yellow 28 BY28 dye in aqueous solution. The influence of experimental variables such as reaction time, NZVI particle dosage and pH were studied on the decolorization of BY28. Mixing an aqueous solution of 100 mg L...
[ 8 ] - Application of Non-Corrosive Acids in Three-Component, One-Pot Synthesis of Commercial Coumarin Dye
The efficiency of HZSM-5 Zeolite, tungestophosphoric acid (H3PW12O40) and tungestosililic acid (H4O40SiW12) were investigated in three-component, one-pot synthesis of coumarin dyes. These green and noncorrosive acids were highly efficient in synthesis of some coumarin dyes in excellent yield during concurrent formation of coumarin and benzimidazole or benzoxazole heterocycles (e.g. C. I. disper...
[ 9 ] - An Investigation of the Dyeability of Acrylic Fiber Via Microwave Irradiation
Microwave dyeing was carried out under a variety of conditions in terms of the power and time of a microwave to investigate the effects of microwaving on the dyeability of acrylic fibers. It was found that the dyeability of acrylic fibers were significantly improved under microwave irradiation caused by the increased adsorption of the dye into fibers due to the local over heating and an amplifi...
[ 10 ] - Add-on for High Throughput Screening in Material Discovery for Organic Electronics: “Tagging” Molecules to Address the Device Considerations
This work reflects the worth of intelligent modeling in controlling the nanostructure morphology in manufacturing organic bulk heterojunction (BHJ) solar cells. It suggests the idea of screening the pool of material design possibilities inspired by machine learning. To fulfill this goal, a set of experimental data on a BHJ solar cell with a donor structure of diketopyrrolopyrrole (DDP) and ...
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