nano-sbcl5.sio2 and sbcl5.sio2 are bench-top catalysts which are reusable, readily available, versatile andefficient for promotion of many acid catalyzed organic reactions. these catalysts do not need specialprecautions for preparation, handling or storage, and they can be stored at an ambient temperature for monthswithout losing their catalytic activity. 4-dihydropyrimidin-2(1h)-ones(thiones) ...

Thermoresponsive TiO2/SiO2 one-dimensional photonic crystals (Bragg stacks) fabricated via sol–gel processing methods represent a promising class of environmentally responsive nanostructures featuring optically encoded temperature and humidity detection. The thermo-optic response of the layer materials is amplified by their inherent porosity owing to adsorption/desorption of ambient humidity in...

SiO2/SiC interface was investigated with high spatial resolution by super-higher-order scanning nonlinear dielectric microscopy (SHO-SNDM). Comparison of non-oxidized and thermally oxidized 4H-SiC wafer revealed that only 5 minutes oxidation makes the interface quality spatially inhomogeneous. SiC wafers with and without post oxidation annealing (POA) in NO ambient were also compared, which sho...

We theoretically propose and investigate a TM-polarized one-dimensional photonic crystal nanocavity with a horizontal SiO2 slot on a suspended silicon nanobeam via the three-dimensional finite-element method. The ultrahigh quality factor and ultrasmall effective mode volume of 1.5×10(7) and 0.176 half-wavelength cubic of the horizontally SiO2-slotted nanocavity show strong possibilities for rea...

We employ first-principles density functional calculations to explore atomic-level interactions and predict the ideal work of adhesion at the SiO2/nickel and ZrO2/SiO2 interfaces. We find that chemical bonding at the interface serves to strengthen significantly interfaces formed with SiO2, which exhibits significant covalent bonding character, relative to those formed using more ionic oxides, s...

Currently, nanoparticles have gained a great attention in the anti-tumor research area. However, to date, studies on the anti-metastasis action of core-shell SiO2@LDH (LDH: layered double hydroxide) nanoparticles remain untouched. Two emerging aspects considered are establishing research on the controlling delivery effect of SiO2@LDH combined with anti-cancer medicine from a new perspective. Th...

The lower crust of the Mesozoic Sierra Nevada batholith was made up of high MgO, garnet-poor and low MgO, garnet-rich pyroxenites. Both groups are genetically linked and are collectively complementary to the mafic to intermediate Sierran plutons. High MgO pyroxenites represent high pressure cumulates from a mantle-derived hydrous basalt or basaltic andesite, resulting in derivative magmas havin...

Magnetic nanoparticles are frequently coated with SiO2 to improve their functionality and bio-compatibility in a range of biomedical and polymer nanocomposite applications. In this paper, a scalable flame aerosol technology is used to produce highly dispersible, superparamagnetic iron oxide nanoparticles hermetically coated with silica to retain full magnetization performance. Iron oxide partic...

The activation of dihydrogen on silica, silver, and silica-supported silver (9 wt% Ag) was investigated. Both, silica and silver are individually able to dissociate dihydrogen. Silanol groups on silica undergo H→D exchange at 393 K in D2 as detected by IR spectroscopy. HD is observed in temporal analysis of products (TAP) experiments when H2 and D2 are sequentially pulsed on silver at 673 K; ev...