The density and viscosity values at T= (293.15 to 323.15) K for binary mixtures of nitromethane with 2-propanol, 2-butanol and 2-pentanol were measured over the entire composition range. From the experimental data, excess molar volumes, thermal expansion coefficients, excess thermal expansions, partial molar volumes at infinite dilution and deviations in viscosity were calculated. The results w...

the thermodynamic properties of fluids can be predicted using the global equations of state. among these thermodynamic properties of fluids, we choose the densities of the liquid and vapor phases. this paper considers the application of the crossover model to the vapor-liquid rectilinear diameter of sulfurhexafluoride. we also present a comparison of the crossover model equation with the experi...

The recent interpretation of the phonon-roton excitations in superfluid He as a density mode at low wave vector and a quasiparticle excitation at higher Q proposed by Glyde and Griffin is developed. When there is a condensate, no( T ), the quasiparticle response of liquid He, becomes a component of the observed density dynamic structure factor, S(g, to). The quasiparticle and density response f...

quantum chemical calculations, based on density functional theory (dft) method, were performed on calix[4]arene and polychlorinated dibenzo-p-dioxins (pcdds) in gas and liquid phases for comparison purposes. the simulation results show the 1,2,3,4, 6,7,8,9-octachlorodibenzo-p-dioxin (ocdd) is quite a reactive dioxin. this paper attempts to examine the possibility of dioxin adsorption by calix[n...

When rapidly cooled, a liquid undergoes dynamic arrest, forming an amorphous solid commonly called glass. Amorphous solids can also be created by different routes, for example by destabilizing the crystal structure at low temperature by applying pressure or intense radiation, or by depositing gas molecules on very cold substrates. Even though the resulting materials encode information about the...

Global statistics of liquid water content and effective number density of water clouds over ocean derived from combined CALIPSO and MODIS measurements Y. Hu, M. Vaughan, C. McClain, M. Behrenfeld, H. Maring, D. Anderson, S. Sun-Mack, D. Flittner, J. Huang, B. Wielicki, P. Minnis, C. Weimer, C. Trepte, and R. Kuehn NASA Langley Research Center, Hampton, VA, USA NASA Goddard Space Flight Center, ...

Heat transfer coefficient in nucleate pool boiling near critical heat flux at least one orderhigher than the convectional heat transfer modes. In this paper, an experimental setup isdesigned and fabricated to investigate the mechanism of heat transfer from boiling surface tobulk liquid near critical heat flux. The images of pool boiling near the high heat flux regionreveals that the individual ...

Resonant x-ray scattering shows that the bulk structure of the twist-bend liquid crystal phase, recently discovered in bent molecular dimers, has spatial periodicity without electron density modulation, indicating a lattice-free heliconical nematic precession of orientation that has helical glide symmetry. In situ study of the bulk helix texture of the dimer CB7CB shows an elastically confined ...

This paper offers a simple macroscopic approach to the question of the slip boundary condition to be imposed upon the tangential component of the fluid velocity at a solid boundary. Plausible reasons are advanced for believing that it is the energy equation rather than the momentum equation that determines the correct fluid-mechanical boundary condition. The scheme resulting therefrom furnishes...