Graphene oxide (GO) thin films were simply deposited on fluorine doped tin oxide (FTO) substrate via a low-voltage electrodeposition. The GO and GO thin films were characterized by Zeta Potential, X-ray diffraction, Ultraviolet-Visible spectroscopy, atomic force microscopy, Fourier transform infrared spectroscopy, field emission scanning electron microscopy and energy dispersive X-ray spectrosc...

Metal-free catalysts, such as graphene/carbon nanostructures, are highly cost-effective to replace expensive noble metals for CO2 reduction if fundamental issues, such as active sites and selectivity, are clearly understood. Using both density functional theory (DFT) and ab initio molecular dynamic calculations, we show that the interplay of N-doping and curvature can effectively tune the activ...

The interaction of nucleobases (NBs) with the surface of silicon doped graphene (SiGr) and defective silicon doped graphene (dSiGr) has been studied using electronic structure methods. A systematic comparison of the calculated interaction energies (adsorption strength) of NBs with the surface of SiGr and dSiGr with those of pristine graphene (Gr) has also been made. The doping of graphene with ...

We theoretically investigate the frictional drag induced by the Coulomb interaction between spatially separated massless and massive fermions in the Boltzmann regime and at low temperatures. As a model system, we use a double-layer structure composed of a two-dimensional electron gas (2DEG) and an n-doped graphene layer. We analyze this system numerically and also present analytical formulas fo...

Novel uses for 2-dimensional materials like graphene and hexagonal boron nitride (h-BN) are being frequently discovered especially for membrane and catalysis applications. Still however, a great deal remains to be understood about the interaction of environmentally and industrially relevant molecules such as water with these materials. Taking inspiration from advances in hybridising graphene an...

In order to disclose the reason that the N-doped carbon support can enhance the stability of Au-based catalysts for acetylene hydrochlorination, we established a big graphene cluster model of C110H28 to investigate the effect of different nitrogen-doped carbon supports on three kinds of gold species models of Au dimers, Au2Cl2 and Au2Cl6, through DFT calculations. Comparing the adsorption energ...

Photoluminescent graphene quantum dots (GQDs) have received enormous attention because of their unique chemical, electronic and optical properties. Here a series of GQDs were synthesized under hydrothermal processes in order to investigate the formation process and optical properties of N-doped GQDs. Citric acid (CA) was used as a carbon precursor and self-assembled into sheet structure in a ba...

A possible approach to achieve quasi-freestanding graphene on a substrate for technological purpose is the intercalation of alkali metal atoms. Cs intercalation between graphene and Ni(111) therefore is investigated using density functional theory, incorporating van der Waals corrections. It is known that direct contact between graphene and Ni(111) perturbs the Dirac states. We find that Cs int...

Title of Document: KELVIN PROBE MICROSCOPY STUDIES OF EPITAXIAL GRAPHENE ON SiC(0001). Alexandra Elizabeth Curtin, PhD., 2011 Directed By: Professor Michael S. Fuhrer, Department of Physics, Center for Nanophysics and Advanced Materials (Director) and the Materials Research Science and Engineering Center. Epitaxial graphene on SiC(0001) presents a promising platform for device applications and ...

Heteroatom doping into the graphitic frameworks have been intensively studied for the development of metal-free electrocatalysts. However, the choice of heteroatoms is limited to non-metallic elements and heteroatom-doped graphitic materials do not satisfy commercial demands in terms of cost and stability. Here we realize doping semimetal antimony (Sb) at the edges of graphene nanoplatelets (Gn...