Gas evolution during electrochemical deposition has long been regarded as undesired and deliberately suppressed. Here, we show a new role of electrochemically evolved hydrogen bubbles, serving as both templates and reducing agent to form hollow Au nanoparticles via electroless deposition. Hollow gold nanoparticles with a complete nanocrystalline shell and a 50 nm hollow core were fabricated. By...

Poly(vinylidene-fluoride-co-trifluoroethylene) (P(VDF-TrFE)) ferroelectric nanotube arrays were fabricated using an anodized alumina membrane (AAM) as a template and silver electrodes were deposited on both the outer and inner sides of the nanotubes by an electroless plating method. The nanotubes have the unique structure of being sealed at one end and linked at the open end, thus preventing el...

Cu 2 O/Si radial nanowire (NWs) array heterojunctions were prepared by depositing O nanoparticles via chemical bath deposition on n-Si arrays that fabricated metal-assisted electroless etching. After 20 cycles of deposition, large numbers with form shells wrap the upper segment each Si nanowire. This method etching offers exceptional simplicity, flexibility, environmental friendliness, and scal...

Electroless nickel plating baths have to be discarded when levels of phosphites build up and interfere with the plating process. OWMC funded research conducted at ORTECH International to determine whether phosphites could be removed from plating bath solution. The first attempt to do this by adsorption on flyash was unsuccessful. However, the use of calcium ion to precipitate calcium phosphite ...

While problems related to CO poisoning still exist for the anode, most of the efficiency loss (80%) in a fuel cell arises due to the cathode. Oxygen reduction at the cathode requires the largest amount of the catalyst in PEM fuel cells due to its lower activity. This problem needs to be solved before mass commercialization of fuel cells can be achieved. The specific objective is to synthesize n...

We have developed a new chemical sensor array by combining polymer-based chemiresistors with a standard integrated circuit technology. We fabricated an array of addressable chemical sensor sites in a CMOS process, and then performed a post-processing step of electroless gold to create sensor contacts. We create sensors by spraying a mixture of nonconductive polymers and carbon black particles o...

he inherent lightness and good strength-to-weight ratio of T magnesium has focused attention on increasing applications in aerospace and allied fields. Its density is two thirds that of aluminum-a conventional structure material for aerospace. Magnesium has one drawback: It is prone to atmospheric corrosion. Further, because of its high chemical affinity for aqueous solutions, it is categorized...