Abstract CF x deliver the ultra-high theoretical specific capacity. Nevertheless, its solvent co-intercalation for rechargeable Na–ion battery cathodes has lacked investigation. Here, we explored co–intercalation behaviour with 1 M NaPF 6 in PC or FEC various and found that is conducive to extended discharge voltage window 1.0 V. Among them, F-CF 0.88 present a discharge-specific capacity first...

The electronic structure and magnetic properties of the graphene/Fe/Ni(111) system were investigated via combination of the density functional theory calculations and electron-spectroscopy methods. This system was prepared via intercalation of thin Fe layers (1 ML) underneath graphene on Ni(111) and its inert properties were verified by means of photoelectron spectroscopy. Intercalation of iron...

A Monte Carlo simulation of a two-dimensional lattice gas with free boundaries is used to study the effects of surface and size on the chemical potential-composition curves of intercalation compounds. In particular we are interested in electrochemically active nanosize lithium intercalation compounds. Both surface and size effects were found to modify the chemical potential versus composition b...

the entro y s of intercalation compounds from W describe the first measurements of changes in ropy e e d 1 of intercalation accurately describes the variation etr of electrochemical cells. A lattice-gas mo e e calorime y rature T with no adjustable parameters. This agreement of (ils/Bx)T with x in Li„Mo6se& at fixed temperature t j L M Se for x & 1 are randomly distributed over a single type of...

Epithelial cell movements, such as those that occur during cell intercalation, largely contribute to the formation of epithelial structures during the morphogenesis of multicellular organisms. As the architecture of epithelial tissues relies on strong adhesion between cells at adherens junctions (AJs), the intercalation or rearrangements of epithelial cells might be controlled by modulating the...

Few-layer graphene has been prepared by electrochemical intercalation of graphite cathode using Na/ dimethyl sulfoxide complexes as intercalation agent. By adding thionin acetate salt into the electrolyte, the exfoliated graphite is stabilized and further exfoliated into few-layer graphene. Raman and X-ray photoelectron spectra indicate that the graphene material has lower content of defects an...

Intercalation of foreign species can induce structural evolution and phase transition 2D materials. In article number 2000581, Liang Zhen, Cheng-Yan Xu, co-workers summarize recent progress on electrochemical intercalation into atomically thin The relationship between materials, structures, properties during the atoms/ions/molecules layered their implication for device applications, are highlig...

Exfoliated poly (Chloromethyl styrene-co-styrene)-g-polyacrylonitryle/organo- modified montmorillonite [P(CMSt-co-St)-g-PAN/O-MMT] nanocomposite was synthesized through solution intercalation method by using atom transfer and nitroxide mediated radical polymerization. At first, poly (chloromethyl styrene-costyrene) copolymer was synthesized by nitroxide - mediated “living” free radical polyme...

In this study, the main objective is the preparation and the characterization of a modified Algerian bentonite based adsorbent by intercalation with hexadecyltrimethylammonium bromide (HDTMA). Natural and modified bentonites were characterized using thermogravimetric analysis (TGA), X-ray diffraction (XRD) and infrared spectroscopy (FTIR). The X-ray results indicate that the geometry of the int...

Conjugation of an anthracycline to a triplex-forming oligonucleotide (TFO) allows delivery of this drug to a specific DNA site, preserving the intercalation geometry of this class of anticancer agents. Conjugate 11, in which the TFO is linked via a hexamethylene bridge to the O-4 on the D ring of the anthraquinone moiety, affords the most stable triple helix, through intercalation of the planar...