Small carbon clusters (Cn, n = 2-15) are produced in a molecular beam by pulsed laser vaporization and studied with vacuum ultraviolet (VUV) photoionization mass spectrometry. The required VUV radiation in the 8-12 eV range is provided by the Advanced Light Source (ALS) at the Lawrence Berkeley National Laboratory. Mass spectra at various ionization energies reveal the qualitative relative abun...

Vertical ionization energies of the nucleosides cytidine and deoxythymidine in water, the lowest ones amounting in both cases to 8.3 eV, are obtained from photoelectron spectroscopy measurements in aqueous microjets. Ab initio calculations employing a nonequilibrium polarizable continuum model quantitatively reproduce the experimental spectra and provide molecular interpretation of the individu...

Recent multi-photon ionization (MPI) experiments on uracil revealed a fragment ion at m/z 84 that was proposed as a potential marker for ring opening in the electronically excited neutral molecule. The present MPI measurements on deuterated uracil identify the fragment as C3H4N2O (uracil less CO), a plausible dissociative ionization product from the theoretically predicted open-ring isomer. Equ...

The electronic structure and photofragmentation in outer and inner valence regions of Se(n) (n ≤ 8) clusters produced by direct vacuum evaporation have been studied with size-selective photoelectron-photoion coincidence technique by using vacuum-ultraviolet synchrotron radiation. The experimental ionization potentials of these clusters were extracted from the partial ion yield measurements. The...

We demonstrate a tool for quantitative measurements in the extreme ultraviolet (EUV) spectral region measuring spatially resolved atomic ionization products at the focus of an EUV beam. The ionizing radiation is a comb of the 11(th)-15(th) harmonics of a Ti:Sapphire femtosecond laser beam produced in a Xenon gas jet. The spatial ion distribution at the focus of the harmonics is recorded using a...

One-photon multiple ionization is a signature of dynamical electron correlations in atoms and small molecules, as observed in the Auger process when Auger electron emission follows core-shell ionization. In such a process, the high energy needed to remove several electrons is due to the strong Coulombic attraction between the last departing electron(s) and the ionic core. Multiply negatively ch...

Abstract 2+We present a methodology for the use of sulphur as global metallicity tracer in galaxies, allowing performing complete abundance analysis using only red-to-near-infrared spectral region. We have applied it to compilation high-quality data split into two samples: H ii regions (DHR) spiral and irregular dwarf galaxies dominated by strong starburst (H Gal). Sulphur abundances been deriv...

Intense-field many-body S-matrix theory (IMST) provides a systematic ab initio approach to investigate the dynamics of atoms and molecules interacting with intense laser radiation. We review the derivation of IMST as well as its diagrammatic representation and point out its advantage over the conventional ‘prior’ and ‘post’ expansions which are shown to be special cases of IMST. The practicalit...

We developed a new computer code which is able to treat the time dependent photoand collisional ionization of gaseous nebulae together with the consistent energy balance for arbitrary numbers of elements, ions and line transitions. The intention of this paper is to describe the basic numerical methods and a few test calculations as being parts of full spherically symmetric radiation-gasdynamic ...

Terahertz (THz) electromagnetic wave has been widely used as a spectroscopic probe to detect the collective vibrational mode in vast molecular systems and investigate dielectric properties of various materials. Recent technological advances in generating intense THz radiation and the emergence of THz plasmonics operating with nanoscale structures have opened up new pathways toward THz applicati...