We have performed a detailed study of the thermodynamics of the titration process in an isothermal titration calorimeter with full cells. We show that the relationship between the enthalpy and the heat measured is better described in terms of the equation Delta H = W(inj) + Q (where W(inj) is the work necessary to carry out the titration) than in terms of DeltaH = Q. Moreover, we show that the ...

The method of Unrestricted Harmonic Balance (UHB) as exposed and applied to purely t imedependent systems, stiff systems, and chemical waves in the preceding 3 papers is extended to the case of transcendental functions. So, e.g., exponential functions even in mass action kinetics systems occur, if a wider range of temperature is considered as is the case in continuous stirred tank reactors (CST...

Abstract The strain variation during the isothermal holding under constant stress was studied in quenched or annealed Ni5 1 Ti 4 9 alloy samples. found both samples and this completely recovered on subsequent unloading heating. This allowed to conclude that caused by martensitic transformation. It maximum value of depended heat treatment. equal 0.5 % sample it 6 sample. assumed formation Ni 3 p...

Thermal spreading resistance is an important phenomenon in contacting bodies and local heating e.g. laser heating. In contacting bodies, the real area of contact is typically less than 2% of the nominal contact area. In practice, due to random nature of contacting surfaces, the actual shape of microcontacts is unknown; therefore, it is advantageous to have a model applicable to any arbitrary-sh...

An immersed-boundary method, previously developed for flow-field simulation, is extended to study heat-transfer problems of flow over a circular cylinder. The Dirichlet-type isothermal temperature boundary conditions and the Neumann-type iso-heat-flux boundary conditions are both implemented. To verify the accuracy of the simulation method, L2-norm are computed to test the order of accuracy of ...

in the present study, the capability of accumulative roll bonding (arb) and subsequent heat-treatment to fabricate solid solution from a multilayered cu/zn/al was investigated. two post-heat treatment (one-step and two-step) routes were proposed. in the first, the arb processed material was heated to 800 c for 5:30 hours and allowed to cool slowly in a furnace (one-step route). in the second (t...

The effect of partial slip and temperature dependent fluid properties on the MHD mixed convection flow from a heated, non-linearly stretching surface in the presence of radiation and non-uniform internal heat generation/absorption is investigated. The velocity of the stretching surface was assumed to vary according to power-law form. Thermal transport is analyzed for two types of non-isothermal...

Analysis of intrinsic irreversibility and heat transfer in a buoyancy-driven changeable viscosity liquid along an incline heated wall with convective cooling taking into consideration the heated isothermal and isoflux wall is investigated. By Newton’s law of cooling, we assumed the free surface exchange heat with environment and fluid viscosity is exponentially dependent on temperature. Appropr...

Literature about entropy generation analysis of a wavy enclosure is scare. In this paper. a FORTRAN cod using an explicit finite-volume method was provided for estimating the entropy production due to the natural convection heat transfer in a cosine wavy absorber solar collector. The volumetric entropy generation terms both the heat transfer term and the friction term were straightly calculated...

In this study, two-dimensional pulsating unsteady flow of nanofluid through a rectangular channel with isothermal walls is investigated numerically. The set of resultant algebraic equations is solved simultaneously using SIMPLE algorithm to obtain the velocity and pressure distribution within the channel. The effects of several parameters, such as volume fraction of different nanoparticles, Rey...