Liquid methanol at densities up to rhorho(0) = 1.7 was studied by NMR in a specially designed diamond-anvil cell. Methyl and hydroxyl resonances have been separately observed at pressures to 43 kbars which exceeds equilibrium freezing pressure of methanol. The chemical shift difference between methyl and hydroxyl protons increases nonlinearly with increasing density, indicating a noticeable dec...

Effects of light intensity gradient on development of intricate hierarchical morphology of semicrystalline polyethylene oxide (PEO) and photoreactive diacrylate (DA) blends undergoing photopolymerization-induced crystallization have been demonstrated experimentally and theoretically. The melting temperature of PEO was found to decline upon addition of DA monomer. A solid-liquid phase diagram ha...

The gas-liquid phase transition of the three-dimensional Lennard-Jones particles system is studied by molecular dynamics simulations. The gas and liquid densities in the coexisting state are determined with high accuracy. The critical point is determined by the block density analysis of the Binder parameter with the aid of the law of rectilinear diameter. From the critical behavior of the gas-l...

Classical molecular dynamics simulations are performed on LiF in the framework of the polarizable ion model. The overlap repulsion and polarization terms of the interaction potential are derived on a purely non-empirical, first-principles basis. For the dispersion, three cases are considered: a first one in which the dispersion parameters are set to zero and two others in which they are include...

This paper describes the design of a liquid-propellant-powered hot-gas actuator appropriate for human-scale powerautonomous robots. The motivation for this work is the development of a lightweight actuation system with system energy and power densities significantly greater than a DC motor and battery combination. The proposed design of a liquid-fueled actuator is presented, followed by a therm...

The boson peak in deeply cooled water confined in nanopores is studied to examine the liquid-liquid transition (LLT). Below ∼180  K, the boson peaks at pressures P higher than ∼3.5  kbar are evidently distinct from those at low pressures by higher mean frequencies and lower heights. Moreover, the higher-P boson peaks can be rescaled to a master curve while the lower-P boson peaks can be rescale...

The five-site transferable interaction potential (TIP5P) for water is most accurate at reproducing experimental data when used with a simple spherical cutoff for the long-ranged electrostatic interactions. When used with other methods for treating long-ranged interactions, the model is considerably less accurate. With small modifications, a new TIP5P-like potential can be made which is very acc...

By well-established theoretical means, it is now possible to calculate thermodynamic properties of elemental crystals and liquids to an accuracy matching that of available low-pressure experiments; it is also known that the neglect of anharmonicity and electron-phonon interactions introduces errors smaller than 5% at low pressures. To check this theoretical framework and the validity of these a...

We analyze the stability of small bubbles in a closed system with fixed volume, temperature, and number of molecules. We show that there exists a minimum stable size of a bubble. Thus there exists a range of densities where no stable bubbles are allowed and the system has a homogeneous density which is lower than the coexistence density of the liquid. This becomes possible due to the finite liq...

The analytic equation of state of nonideal Coulomb plasmas consisting of pointlike ions immersed in a polarizable electron background [G. Chabrier and A. Y. Potekhin, Phys. Rev. E 58, 4941 (1998)] is improved, and its applicability range is considerably extended. First, the fit of the electron screening contribution in the free energy of the Coulomb liquid is refined at high densities where the...