a method for predicting liquid densities of binary mixtures from heat of vaporization and liquid densityat boiling point temperature (δhvap and n b ρ ) as scaling constants, is presented. b2(t) follows a promisingcorresponding-states principle. calculation of α(t) and b(t), the two other temperature-dependentconstants of the equation of state, are made possible by scaling. as a result δhvap and...

in this work an analytical equation of state has been employed to calculate the pvt properties ofternary refrigerant mixtures. the theoretical eos is that of ihm, song and mason, which is based onstatistical-mechanical perturbation theory, and the two constants are enthalpy of vaporization δhvapand molar density ρnb, both at the normal boiling temperature. the following three temperaturedepende...

A method for predicting liquid densities of binary mixtures from heat of vaporization and liquid densityat boiling point temperature (ΔHvap and n b ρ ) as scaling constants, is presented. B2(T) follows a promisingcorresponding-states principle. Calculation of α(T) and b(T), the two other temperature-dependentconstants of the equation of state, are made possible by scaling. As a result ΔHvap and...

In the present research, three different architectures were investigated to predict the coefficients of the Daubert and Danner equation for calculation of saturated liquid density. The first architecture with 4 network input parameters including critical temperature, critical pressure, critical volume and molecular weight, the second architecture with 6 network input parameters including the on...

the thermodynamic properties of fluids can be predicted using the global equations of state. among these thermodynamic properties of fluids, we choose the densities of the liquid and vapor phases. this paper considers the application of the crossover model to the vapor-liquid rectilinear diameter of sulfurhexafluoride. we also present a comparison of the crossover model equation with the experi...

Measurements are reported of the liquid and liquid–solid mixture (mush) densities of succinonitrile–acetone (SCN– ACE) alloys for use in crystal growth and solidification studies. The measured data for the liquid is analyzed and consolidated into a correlation that expresses the liquid density as a function of composition and temperature. This correlation also allows for the calculation of the ...

The thermodynamic properties of fluids can be predicted using the global equations of state. Among these thermodynamic properties of fluids, we choose the densities of the liquid and vapor phases. This paper considers the application of the crossover model to the vapor-liquid rectilinear diameter of sulfurhexafluoride. We also present a comparison of the crossover model equation with ...

a second virial coefficient correlation suitable for two different temperatures ranges, (t*)-2£180 and (t*)-2>180, where t* is rt/dhvap is presented. the equation of state can be calculated for different, complicated non-polar, and slightly polar liquid mixtures at any temperature over the range from ttp to tc and up to high pressures. the latent heat of vaporization and density at the triple p...

In this paper we present a new thermodynamically consistent phase transition model describing the evolution of a liquid substance, e.g., water, in a rigid container Ω when we freeze the container. Since the density ̺2 of ice with volume fraction β2 , is lower than the density ̺1 of water with volume fraction β1 , experiments for instance the freezing of a glass bottle filled with water show that ...