The present investigation highlights the synthesis of polyaniline (PANI)-coated graphene oxide doped with SrTiO3 nanocube nanocomposites through facile in situ oxidative polymerization method for the efficient removal of carcinogenic dyes, namely, the cationic dye methylene blue (MB) and the anionic dye methyl orange (MO). The presence of oxygenated functional groups comprised of hydroxyl and e...

We use anhydrous ferric chloride (FeCl(3)) to intercalate graphite flakes consisting of 2-4 graphene layers and to dope graphene monolayers. The intercalant, staging, stability, and doping of the resulting intercalation compounds (ICs) are characterized by Raman scattering. The G peak of heavily doped monolayer graphene upshifts to ∼1627 cm(-1). The 2-4 layer ICs have similar upshifts, and a Lo...

Metal sulfides are commonly used in energy storage and electrocatalysts due to their redox centers and active sites. Most literature reports show that their performance decreases significantly caused by oxidation in alkaline electrolyte during electrochemical testing. Herein, S and N co-doped graphene-based nickel cobalt sulfide aerogels are synthesized for use as rechargeable alkaline battery ...

A novel hybrid nanocomposite, PMo11V@N-doped few layer graphene, was prepared by a one-step protocol through direct immobilization of the tetrabutylammonium salt of a vanadium-substituted phosphomolybdate (PMo11V) onto N-doped few layer graphene (N-FLG). The nanocomposite characterization by FTIR and XPS confirmed its successful synthesis. Glassy carbon modified electrodes with PMo11V and PMo11...

After advent of graphene as a saturable absorber many experiments have been conducted to produce short pulse duration pulses. Here, we have measured the properties of flake-graphene saturable absorber mirrors of various flake sizes dependent on fabrication technique. These mirrors enabled us to obtain a large mode-locking bandwidth of 16nm in an erbium-doped fiber laser. Mirrors with large flak...

Hydrogen storage capacities have been studied on newly designed three-dimensional pillared boron nitride (PBN) and pillared graphene boron nitride (PGBN). We propose these novel materials based on the covalent connection of BNNTs and graphene sheets, which enhance the surface and free volume for storage within the nanomaterial and increase the gravimetric and volumetric hydrogen uptake capaciti...

Submitted for the MAR07 Meeting of The American Physical Society Boron doped graphene nanoribbons THIAGO MARTINS, Instituto de Fisica Universidade de Sao Paulo, HIROKI MIWA, Instituto de Fisica, Universidade Federal de Uberlandia, ANTONIO J.R. DA SILVA, A. FAZZIO, Instituto de Fisica Universidade de Sao Paulo — We will present a detailed study of the electronic, magnetic and transport propertie...

Electronic and optical properties of graphene and graphitic ZnO (G/g-ZnO) nanocomposites have been investigated with density functional theory. Graphene interacts overall weakly with g-ZnO monolayer via van der Waals interaction. There is no charge transfer between the graphene and g-ZnO monolayer, while a charge redistribution does happen within the graphene layer itself, forming well-defined ...

Patterned graphene shows substantial potential for applications in future molecular-scale integrated electronics. Environmental effects are a critical issue in a single-layer material where every atom is on the surface. Especially intriguing is the variety of rich chemical interactions shown by molecular oxygen with aromatic molecules. We find that O 2 etching kinetics vary strongly with the nu...

Graphene and single-walled carbon nanotube (SWCNT) have been widely studied because of their extraordinary electrical, thermal, mechanical, and optical properties. This paper describes a novel and flexible method to fabricate all-carbon field-effect transistors (FETs). The fabrication process begins with assembling graphene grown by chemical vapor deposition (CVD) on a silicon chip with SiO2 as...