We present a detailed study of the electronic structure and the stability of C(60) dianions in the gas phase. Monoanions were extracted from a plasma source and converted to dianions by electron transfer in a Na vapor cell. The dianions were then stored in an electrostatic ring, and their near-infrared absorption spectrum was measured by observation of laser induced electron detachment. From th...

 Abstract Background: Transpupillary thermotherapy is a new treatment for subfoveal choroidal neovascularization which needs further evaluation. This study was aimed to evaluate the efficacy of transpupillary thermotherapy on regression of occult subfoveal choroidal neovascularization with or without pigment epithelial detachment in patients with age-related macular degeneration. Methods: In a ...

Experiments were carried out using a flowing-afterglow Langmuir-probe apparatus to measure rate constants for electron attachment to SF6 and thermal detachment from SF6'. In a recent series of papers, these results were combined with new and existing data on nondissociative and dissociative attachment to SF6 and compared to statistical modeling of the various processes involved in the stabiliza...

Nonvalence states of molecular anions play key roles in processes, such as electron mobility, in rare-gas liquids, radiation-induced damage to DNA, and the formation of anions in the interstellar medium. Recently, a class of nonvalence bound anion state has been predicted by theory in which correlation forces are predominantly responsible for binding the excess electron. We present a direct spe...

A low barrier in the reaction pathway between the double Rydberg isomer of OH(3) (-) and a hydride-water complex indicates that the former species is more difficult to isolate and characterize through anion photoelectron spectroscopy than the well known double Rydberg anion (DRA), tetrahedral NH(4) (-). Electron propagator calculations of vertical electron detachment energies (VEDEs) and isosur...

The equilibrium structure, stability, and electronic properties of the Al(13)X (X=H,Au,Li,Na,K,Rb,Cs) clusters have been studied using a combination of photoelectron spectroscopy experiment and density functional theory. All these clusters constitute 40 electron systems with 39 electrons contributed by the 13 Al atoms and 1 electron contributed by each of the X (X=H,Au,Li,Na,K,Rb,Cs) atom. A sy...

It is believed that guanine, a basic component of DNA and RNA, has the smallest affinity to an excess electron among all nucleic acid bases. Our experimental and computational findings indicate, however, that many so far neglected tautomers of guanine support adiabatically bound anionic states in the gas phase. The computed values of electron vertical detachment energy for the most stable anion...

High resolution anion photodetachment spectra are presented for the methoxide anion and its fully deuterated counterpart. The spectra were obtained with slow electron velocity-map imaging. Improved electron affinities are determined for CH3O as 1.5690+/-0.0019 eV and for CD3O as 1.5546+/-0.0019 eV. The spectra resolve many features associated with spin-orbit and vibronic coupling that were not ...

The photoelectron group delay, also known as the Wigner time delay (WTD), is examined in photodetachment of ${\mathrm{H}}^{\ensuremath{-}}\phantom{\rule{0.16em}{0ex}}$ and ${\mathrm{Li}}^{\ensuremath{-}}\phantom{\rule{0.16em}{0ex}}$ ions near their lowest inelastic double detachment thresholds. These threshold processes promoting remaining bound electron to an excited state or ejecting it conti...

In this work we provide experimental insights into the impact of plasma-molecule interactions on target ion flux decrease during divertor detachment achieved through a core density ramp in TCV tokamak. Our improved analysis hydrogen Balmer series shows that processes are strongly contributing to intensities and substantially alter particle balance. We find Molecular Activated Recombination (MAR...