It has long been recognised that at elevated temperatures surface energy is the driving force for the distribution of melts and fluids among crystalline grains. While for ideal isotropic systems only two parameters, the dihedral angle (the ratio of grain boundary energy to solid-liquid surface energy) and the melt fraction are needed to completely constrain the melt distribution, anisotropic sy...

A bulge is an extra, unpaired nucleotide on one strand of a DNA double helix. This paper describes bulge-specific strand scission by the DNA intercalating/cleaving drugs neocarzinostatin chromophore (NCS-C), bleomycin (BLM), and methidiumpropyl-EDTA (MPE). For this study we have constructed a series of 5'-32P end labeled oligonucleotide duplexes that are identical except for the location of a b...

This paper reports a number of recent developments in the intercalation chemistry of Al(OH)(3). From Rietveld refinement and solid-state NMR, it has been possible to develop a structural model for the recently reported [M(II)Al(4)(OH)(12)](NO(3))(2)·yH(2)O family of layered double hydroxides (LDHs). The M(2+) cations occupy half of the octahedral holes in the Al(OH)(3) layers, and it is thought...

Perturbations to the 1H and 31P chemical shifts of DNA resonances together with twenty-four intermolecular nuclear Overhauser effects show that the anthracycline antibiotic arugomycin intercalates between the basepairs of the hexamer duplex d(5'-GCATGC)2 at the 5'-CpA and 5'-TpG binding sites. In the complex two drug molecules are bound per duplex with full retention of the dyad symmetry. Arugo...

the interaction between isatin-β-thiosemicarbazone (ibt) and calf thymus dna (ct-dna) was investigated in physiological buffer (ph 7.4) using neutral red (nr) dye as a spectral probe by uv–vis absorption and fluorescence spectroscopy, as well as viscosity measurements. the ibt is stabilized by intercalation in the dna ( k [ibt –dna] =1.03×105 m−1), and displaces the nr dye from the nr–dna comple...

Mantle–melt interaction during melt transport is explored in one generally moves relative to the residual solid phases. This follows from experimental and theoretical studies of the dimension and steady state. We reconsider the equivalence between one-dimensional steady equilibrium transport and batch melting. In equilibrium textures of olivine-dominated, partially molten systems, which indicat...

Recommendations are presented for the nomenclature and terminology of graphite intercalation compounds, i.e. compounds that retain the planarity of the layers in the graphite structure. Not included are compounds with covalent bonding of heteroatoms to the carbon atoms which leads to a sp3 hybridization of the carbon atoms and a corresponding loss of planarity of the layers. Rules for a structu...

The temperature dependence of the open-circuit potential of lithium half-cells was measured for electrodes of carbon materials having different amounts of structural disorder. The entropy of lithium intercalation, DS , and enthalpy of intercalation, DH , were determined over a broad range of lithium concentrations. For the disordered carbons, DS is small. For graphite, an initially large DS dec...