Photoelectron spectra of MgO n n 1 5 reveal a surprising trend: The electron binding energy decreases from n 1 to 4, and then increases from 4 to 5. Ab initio calculations suggest this pattern is related to the electrostatic interaction between the extra electron and the charge distribution of the neutral cluster. This interaction is significant in MgO and MgO 2 5 , for which the lowest nonvani...

Various theories have been proposed to explain the hyperglycaemia-induced pathogenesis of vascular complications of diabetes, including detrimental effects of AGEs (advanced glycation end products) on vascular tissues. Increased formation of the very reactive dicarbonyl compound MGO (methylglyoxal), one of the side-products of glycolysis, and MGO-derived AGEs seem to be implicated in the develo...

The binary MgO–ZnO and CaO–ZnO systems the ternary CaO–MgO–ZnO system were thermodynamically optimized with phase equilibria studies in this study. Bragg-Williams random mixing model was used for solid solutions, while Modified Quasichemical Model liquid solution. thermodynamic optimization conducted using Factsage 8.1 thermochemical software. diagrams fit well experimental results. performed a...

Progressive conversion/shrinking core (PC-SC) models of constant-size cylinders were exploited to interpret the decarburization reactions of MgO-C-Si bricks heated up under blown air. Chemical adsorption/solid (or pore) diffusion mechanisms governed the reaction rate. With 5% silicon, chemical adsorption vanished at 1000 and 1100°C. The oxidation rate lowered then with temperature. This was due...

Nano SiO2 and MgO particles were incorporated into β-tricalcium phosphate (β-TCP) scaffolds to improve the mechanical and biological properties. The porous cylindrical β-TCP scaffolds doped with 0.5 wt % SiO2, 1.0 wt % MgO, 0.5 wt % SiO2 + 1.0 wt % MgO were fabricated via selective laser sintering respectively and undoped β-TCP scaffold was also prepared as control. The phase composition and me...

We report scanning tunneling spectroscopy studies of the electronic structure of 1.5–3 nm 001 textured MgO layers grown on 001 Fe. Thick MgO layers exhibit a bulklike band gap, 5–7 eV, and sparse, localized defect states with characteristics attributable to oxygen and, in some cases, Mg vacancies. Thin MgO layers exhibit an electronic structure indicative of interacting defect states forming ba...

respectively. It has been reported that coating of a thin MgO layer on SnO2 particles results in enhancement of both solar cell performance and catalytic activities. The promoting effect of MgO layer was owing to barrier effect where MgO acts as a barrier layer for charge recombination. We noticed negative shift of flatband (FB) potential of SnO2 with the increase of pH values and coating of a ...

Layered, binary thin-film oxides of NiO, MgO and CaO have been prepared and characterized using low energy electron diffraction, Auger electron spectroscopy, energy loss spectroscopy, ion scattering spectroscopy, and temperature programmed desorption using probe molecules. Epitaxial growth was observed for the NiO–MgO and CaO–NiO systems; however, superior wetting was found for NiO–MgO relative...