background: bromide is found naturally in groundwater and surface water. the rapid growth of industrial activities, drainage of surface runoff, and use of methyl bromide in pesticides has increased bromide discharge to the environment. disinfection of water-containing bromide causes the creation of additional products of organo-halogenated that are considered cancer-causing agents. in this stud...

The rapid separation of inorganic anions was determined by capillary ion chromatography using monolithic silica capillary columns modified with dilauryldimethylammonium bromide. The stability of the modified stationary phase was satisfactory owing to a strong hydrophobic interaction between the lauryl groups of the reagent, even if the eluent did not contain dilauryldimethylammonium ion. Bromid...

In the title compound, [ReBr(C(12)H(9)IN(2))(CO)(3)], the coordination geometry of the Re(I) ion is a distorted fac-ReC(3)BrN(2) octa-hedron, arising from the N,N'-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the 4-iodo-N-(pyridin-2-yl-methyl-idene)aniline ligand is 46.2 (3)°. The bromide ion and its corresp...

The dehalogenation in vivo of brominated aliphatic hydrocarbons such as methyl bromide (1) and bromochloromethane (2) has been demonstrated by recovery of inorganic bromide from blood and urine. The intracellular formation of bromide and methyl alcohol from methyl bromide has been advanced as an explanation for its prolonged toxic effect (3). Evidence for the splitting of chlorinated aliphatic ...

In recent years, ionic liquids have been used in pharmaceutical processes. Therefore, having a deep insight into the ion association behavior of ionic liquids in the presence of a drug is of particular importance. So, in this work, the molar conductivities of the ionic liquids, 1-alkyl-3-methylimidazolium bromide, [CnMIm]Br (n = 4, 6 and 8) in various concentrations of aspirin (ASA) ...

Many enzymes have buried active sites. The properties of the tunnels connecting the active site with bulk solvent affect ligand binding and unbinding and also the catalytic properties. Here, we investigate ligand passage in the haloalkane dehalogenase enzyme LinB and the effect of replacing leucine by a bulky tryptophan at a tunnel-lining position. Transient kinetic experiments show that the mu...

 Background: Bromide is found naturally in groundwater and surface water. The rapid growth of industrial activities, drainage of surface runoff, and use of methyl bromide in pesticides has increased bromide discharge to the environment. Disinfection of water-containing bromide causes the creation of additional products of organo-halogenated that are considered cancer-causing agents. In...

We encountered three patients (Patient I: 39-year-old man, Patient II: 34-year-old woman, and Patient III: 5-year-old girl) with acute methyl bromide poisoning, which had occurred as a result of exposure to the gas that leaked from methyl bromide cans stored in a warehouse of a seedling farm. Since all three patients exhibited almost the same initial symptoms, i.e., severe vomiting, tonic convu...

in recent years, ionic liquids have been used in pharmaceutical processes. therefore, having a deep insight into the ion association behavior of ionic liquids in the presence of a drug is of particular importance. so, in this work, the molar conductivities of the ionic liquids, 1-alkyl-3-methylimidazolium bromide, [cnmim]br (n = 4, 6 and 8) in various concentrations of aspirin (asa) in acetonit...