The first photoactivated doped quantum dot vector for metal-ion release has been developed. A facile method for doping copper(I) cations within ZnS quantum dot shells was achieved through the use of metal-dithiocarbamates, with Cu(+) ions elucidated by X-ray photoelectron spectroscopy. Photoexcitation of the quantum dots has been shown to release Cu(+) ions, which was employed as an effective c...

Functionally graded materials (FGMs) are compositionally gradient materials. They can achieve the controlled distribution of the desired characteristics within the same bulk material. We describe a functionally graded (FG) metal-phosphor adapting the concept of the FGM; copper (Cu) is selected as a metal and Cu- and Cl-doped ZnS (ZnS:Cu,Cl) is selected as a phosphor and FG [Cu]-[ZnS:Cu,Cl] is f...

ZnS:Cu,Cl,Mn,Te, which shows red AC powder electroluminescence (ACPEL) emission, was synthesized using a conventional wet synthesis and a sealed vessel method. The photoluminescence (PL) and ACPEL were characterized. After the second firing, 0.5 wt% tellurium (Te)-doped ZnS: Cu,Cl,Mn,Te phosphor shows almost red PL emission from the T1– A1 transition of Mn 21 ions, which are affected by the Te....

We describe an optically transparent, laser heated, thermoluminescent glass dosimeter that is used for fiber-optic-coupled remote radiation monitoring. The glass consists of ZnS nanocrystallites embedded in a Vycor glass host, doped with Cu and Nd ions. An 807 nm, 1 W GaAlAs laser is used to rapidly heat microscopic regions, surrounding the Nd ions, in the composite glass to stimulate blue-gree...

Ultrasonic-assisted method was applied for preparation of Cu+2-doped ZnS nanoparticles (mole fractions of Cu+2 ions are 0.000, 0.015, 0.030 and 0.060) in water as a template-free and green method at 30 min. The prepared nanoparticles were investigated by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and UV–Vis diffuse reflectance spectra (DRS)...

Doped ZnS quantum dots (QDs) have a longer dopant emission lifetime and potentially lower cytotoxicity compared to other doped QDs. The liver is the key organ for clearance and detoxification of xenobiotics by phagocytosis and metabolism. The present study was designed to synthesize and evaluate the hepatotoxicity of Mn-doped ZnS QDs and their polyethylene glycol-coated counterparts (1 mg/kg an...

Pure and doped ZnS nanocrystalline phosphors were prepared at room temperature using a chemical synthesis method. Transmission electron microscopy observation shows that the size of the ZnS crystals is in the 2-3 nm range and SAED pattern confirms the cubic and crystalline nature of the observed samples, which are in agreement with X-Ray analysis. Interesting luminescence characteristics such a...

Reducing the oxidative capacity of holes (h(+)) in the valence band (VB) of ZnS is one of the most effective ways to prevent the photocatalyst from photocorrosion. In this work, ZnS doped only with nitrogen was prepared for the first time by nitriding ZnS powder in an NH3 atmosphere. We demonstrate theoretically and experimentally that the valence band maximum (VBM) rises obviously by N-doping ...

For the first time, we report the applications of Mn(2+)-doped ZnS@cysteine nanoparticles (NPs) as matrices for analysis of coccidiostats (lasalocid, monensin, salinomycin and narasin) and peptide mixtures (Met-enk, Leu-enk, HW6 and gramicidin) in surface-assisted laser desorption/ionization time-of-flight mass spectrometry (SALDI-TOF MS). The Mn(2+)-doped ZnS@cysteine NPs have been successfull...

Thin films of indium doped zinc sulfide (ZnS) for different indium (In) concentrations (x=0.0 - 0.8) were deposited onto glass substrate by spray pyrolysis method at 523K temperature. Aqueous solution of zinc acetate, indium chloride and thiorea were used to deposit the In-Zn-S film. The deposited thin films were characterized by Energy dispersive X-ray (EDX), Scanning electron microscopy (SEM)...