Ten organoimido polyoxometalate (POM)-based chromophores have been synthesized and studied by hyper-Rayleigh scattering (HRS), Stark and Resonance Raman spectroscopies, and density functional theory (DFT) calculations. HRS β0 values for chromophores with resonance electron donors are significant (up to 139 × 10-30 esu, ∼5 times greater than that of the DAS+ cation), but systems with no donor, o...

A simple and facile one-step method for the synthesis of an organic dye-functionalized polyoxometalate (POM) hybrid with visible-light photo-response was reported. The POM hybrid was fully characterized via single crystal XRD, powder XRD, FTIR and elemental analysis. The reaction of the organic dye with inorganic salts gave the dye-functionalized POM (MoBB3), in which the POM cluster was formed...

Hepatic echinococcosis (HE) is a prevalent health problem, and there is limited published information regarding HE surgery. On the other hand, postoperative morbidity (POM) has not varied significantly. The aim of this study was to describe early and late outcomes in terms of POM of a series of patients with non-complicated liver hydatid cysts (NLHC) treated surgically. Prospective cohort. We i...

Abstract The elongational rheology of blends a polystyrene (PS) Pom-Pom with two linear polystyrenes was recently reported by Hirschberg et al. (J. Rheol. 2023, 67:403–415). PS280k-2x22-22k self-entangled backbone ( M w,bb = 280 kg/mol) and 22 entangled sidearms w,a at each the branch points blended weight fractions from 75 to 2 wt% having w 43 kg/mol (PS43k) 90 (PS90k), respectively. While pur...

There are many effective chemothereutic agents used in influenza disease which some of them inhibit virus replication by interfering with FluV (influenza virus) viral binding or its penetration into cell membrane. A series of polyoxometalates compounds such as POM-523 and PM-504 have been synthesized and have showed inhibitory effects on viruses. In this study we examined anti influenza activit...

This study investigates the numerical solution of viscoelastic flows using two contrasting high-order finite volume schemes. We extend our earlier work for Poiseuille flow in a planar channel and the single equation form of the extended pom-pom (SXPP) model [1], to determine steady-state solutions for planar 4:1 sharp contraction flows. The numerical techniques employed are time-stepping algori...

We numerically investigate the stability problem of the injection molding process. It was indicated by Bulters and Schepens Bulters and Schepens 2000 that surface defects of injection molded products may be attributed to a flow instability near the free surface during the filling stage of the mold. We examine the stability of this flow using the extended Pom–Pom constitutive equations. The mode...

This study investigates the numerical solution of viscoelastic flows using two contrasting high-order finite volume schemes. We extend our earlier work for Poiseuille flow in a planar channel and the single equation form of the extended pom-pom (SXPP) model [1], to determine steady-state solutions for planar 4:1 sharp contraction flows. The numerical techniques employed are time-stepping algori...

A wetting and drying scheme (WDS) is developed to incorporate into a three-dimensional sigmacoordinate coastal ocean model (POM; Blumberg and Mellor, 1983) with proposing an extended logarithmic profile within and above bed boundary layers to accurately simulate 3D hydrodynamics in extremely shallow coastal seas. While the WDS is simplistically formulated, it can selectively retain the computat...

Abstract A dramatically changing business landscape characterized by volatility and uncertainty (which in turn are driven unpredictable alterations of conditions such factors as geopolitical events, climate changes, disasters—natural human causes, reduction food, potable water, critical materials supply along with environmental contamination), has created a situation whereby rethink Production ...