Ultrafast (sub-picosecond) internal conversion can occur between electronic states without energetically accessible conical intersections. For that, the molecule must remain in a region of at least weak nonadiabatic coupling, multiplying odds transition, each with small probability. This phenomenon is discussed simple analytical model correlating instantaneous probability to lifetime.

Analytic expressions were derived for the compressibility factor and residual internal energy of the square-well plus Sutherland fluid. In this derivation, we used the second order Barker-Henderson perturbation theory based on the macroscopic compressibility approximation together with an analytical expression for radial distribution function of the reference hard sphere fluid. These properties...

We consider piezoelectric flow energy harvesting in an internal flow environment with the ultimate goal powering systems such as sensors in deep oil well applications. Fluid motion is coupled to structural vibration via a cantilever beam placed in a converging-diverging flow channel. Two designs were considered for the electromechanical coupling: first; the cantilever itself is a piezoelectric ...

One of the pivotal questions in the dynamics of the oceans is related to the cascade of mechanical energy in the abyss and its contribution to mixing. Here, we propose a unique self-consistent experimental and numerical set up that models a cascade of triadic interactions transferring energy from large-scale monochromatic input to multiscale internal wave motion. We also provide, for the first ...

Wintertime stratification on Oregon’s continental shelf often produces a near-bottom layer of dense fluid that acts as an internal waveguide on which nonlinear internal waves propagate. Shipboard profiling and bottom lander observations capture disturbances that exhibit properties of internal solitary waves, bores and gravity currents. Wave-like pulses are highly turbulent (instantaneous bed st...

This paper introduces energy exchanges, a set of abstractions that allow applications to help hardware and operating systems manage power and energy consumption. Using annotations, energy exchanges dictate when, where, and how to trade performance or accuracy for power in ways that only an application’s developer can decide. In particular, the abstractions offer audits and budgets which watch a...