The methanol to olefins conversion over zeolite catalysts is a commercialized process to produce light olefins like ethene and propene but its mechanism is not well understood. We herein investigated the formation of ethene in the methanol to olefins reaction over the H-ZSM-5 zeolite. Three types of ethylcyclopentenyl carbocations, that is, the 1-methyl-3-ethylcyclopentenyl, the 1,4-dimethyl-3-...

Fischer-Tropsch synthesis is a promising route for production of light olefins via CO hydrogenation over transition metals. Co is one of the most active metals for Fischer-Tropsch synthesis. Some different variables such as preparation parameters and operational factors can strongly affect the selectivity of Fischer-Tropsch synthesis toward the special products. In the case of preparat...

Light olefins are the main building blocks used in petrochemical and chemical industries for production of different components such as polymers, synthetic fibers, rubbers, plastic materials. Currently, steam cracking hydrocarbons is technology light olefins. In cracking, pyrolysis feedstocks occurs furnace, where hydrocarbon feed first mixed preheated convection section then enter furnace radi...

A visible light mediated, but photocatalyst-free method for the oxidative α-CH functionalization of tertiary amines with a broad scope of carbon- and heteroatom nucleophiles using polyhalomethanes has been developed. In addition, the pivotal visible light triggered activation of polyhalomethanes offers mild conditions for efficient Kharasch-type additions onto non-activated olefins. Preliminary...

ITQ-69 has been synthesized, characterized, and its application as selective adsorbent for light olefins/paraffins tested.

In order to enhance the catalytic performance of SAPO-34 catalyst for the reaction of methanol to olefins (MTO), ultrasonic and microwave-assisted aging method were employed in static hydrothermal method to synthesize nano-sized SAPO-34. The effects of the application of this method on the chemical composition, morphology, surface area and total acidity of SAPO-34 were characterized by XRD, FE-...

Current article describes application of zeolites in fluid catalytic cracking (FCC). The use of several zeolitic additives for the production light olefins and reduction of pollutants is described. Application of zeolites as fluid catalytic cracking (FCC) catalysts and additives due to the presence of active acid sites in the zeolite framework  increase the formation of desired cracking product...

Methanol is a key reaction intermediate formed on MnO x that synergistically reacts with SAPO-34 to produce light olefins.